Seawater evaporation and purification powered by solar energy are considered as a promising approach to alleviate the global freshwater crisis, and the development of photothermal materials with high efficiency is imminent. In this study, cellulose nanofiber (CNF)/MXene/Ni chain (CMN) aerogels were successfully synthesized by electrostatic force and hydrogen bond interaction force. CMN10 achieved a favorable evaporation rate as high as 1.85 kg m− 2 h− 1 in pure water, and the corresponding evaporation efficiency could be up to 96.04%. Even if it is applied to seawater with multiple interference factors, its evaporation rate can still be 1.81 kg m− 2 h− 1. The superior seawater evaporation activity origins from the promoted separation of photoexcited charges and photothermal conversion by the synergy of Ni chain and MXene, as well as the water transport channel supported by the 3D structure frame of CNF. Most importantly, CMN aerogel can maintain water vapor evaporation rates above 1.73 kg m− 2 h− 1 under extreme conditions such as acidic (pH 2) and alkaline (pH 12) conditions. In addition, various major ions, heavy metals and organic pollutants in seawater can be rejected by CMN10 during desalination, and the rejection rates can reach more than 99.69%, ensuring the purity of water resources after treatment. This work shows the great potential of CMN aerogel as a high-efficiency solar evaporator and low-cost photothermal conversion material. Cellulose nanofiber (CNF)/MXene/Ni chain (CMN) aerogels demonstrated high evaporation of water from sea water.
Water samples were collected every one hour during July 23-24 1987 from the Minami-Asakawa River and sewage effluents into it. Mearldaily loading and budgets of some bioelements, such as carbon, nitrongen and phosphorrs, were estimated. the fluxeds of suspended matter, organic carbons and ammoioum appeared to remove by self-purification pocesses. On the other hand, those of nitrate, nitrite and chlorophyll a, which were considered to be produced in situ, increased with the river flow. From these results, it was suggested that the river is not only the place for transportation of bioelements but also that for their metabolism.