The (Ga1-xZnx)(N1-xOx) solid solution is attracting extensive attention for photocatalytic water splitting and wastewater treatment owing to its narrow and controllable band gap. To optimize the photocatalytic performance of the solid solution, the key points are to decrease its band gap and recombination rate. In this study, (Ga1-xZnx)(N1-xOx) nanofibers with various Zn fractions are prepared by electrospinning followed by calcination and nitridation. The effect of the composition and crystallinity of electrospun oxide nanofibers on the morphology and optical properties of the obtained solid-solution nanofibers are systematically investigated. The results show that the final shape of the (Ga1-xZnx) (N1-xOx) material is greatly affected by the crystallinity of the oxide nanofibers before nitridation. The photocatalytic properties of (Ga1-xZnx)(N1-xOx) with different Ga:Zn atomic ratios are investigated by studying the degradation of rhodamine B under visible light irradiation.

In this study, (GaN)1-x(ZnO)x solid solution nanoparticles with a high zinc content are prepared by ultrasonic spray pyrolysis and subsequent nitridation. The structure and morphology of the samples are investigated by X-ray diffraction (XRD), field-emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The characterization results show a phase transition from the Zn and Ga-based oxides (ZnO or ZnGa2O4) to a (GaN)1-x (ZnO)x solid solution under an NH3 atmosphere. The effect of the precursor solution concentration and nitridation temperature on the final products are systematically investigated to obtain (GaN)1-x(ZnO)x nanoparticles with a high Zn concentration. It is confirmed that the powder synthesized from the solution in which the ratio of Zn and Ga was set to 0.8:0.2, as the initial precursor composition was composed of about 0.8-mole fraction of Zn, similar to the initially set one, through nitriding treatment at 700oC. Besides, the synthesized nanoparticles exhibited the typical XRD pattern of (GaN)1-x(ZnO)x, and a strong absorption of visible light with a bandgap energy of approximately 2.78 eV, confirming their potential use as a hydrogen production photocatalyst.

Bismuth vanadate (BiVO4) is considered a potentially attractive candidate for the visible-light-driven photodegradation of organic pollutants. In an effort to enhance their photocatalytic activities, BiVO4 nanofibers with controlled microstructures, grain sizes, and crystallinities are successfully prepared by electrospinning followed by a precisely controlled heat treatment. The structural features, morphologies, and photo-absorption performances of the asprepared samples are systematically investigated and can be readily controlled by varying the calcination temperature. From the physicochemical analysis results of the synthesized nanofiber, it is found that the nanofiber calcines at a lower temperature, shows a smaller crystallite size, and lower crystallinity. The photocatalytic degradation of rhodamine-B (RhB) reveals that the photocatalytic activity of the BiVO4 nanofibers can be improved by a thermal treatment at a relatively low temperature because of the optimization of the conflicting characteristics, crystallinity, crystallite size, and microstructure. The photocatalytic activity of the nanofiber calcined at 350oC for the degradation of RhB under visible-light irradiation exhibits a greater photocatalytic activity than the nanofibers synthesized at 400oC and 450oC.

In this study, ultrasonic spray pyrolysis combined with salt-assisted decomposition, a process that adds sodium nitrate (NaNO3) into a titanium precursor solution, is used to synthesize nanosized titanium dioxide (TiO2) particles. The added NaNO3 prevents the agglomeration of the primary nanoparticles in the pyrolysis process. The nanoparticles are obtained after a washing process, removing NaNO3 and NaF from the secondary particles, which consist of the salts and TiO2 nanoparticles. The effects of pyrolysis temperature on the size, crystallographic characteristics, and bandgap energy of the synthesized nanoparticles are systematically investigated. The synthesized TiO2 nanoparticles have a size of approximately 2–10 nm a bandgap energy of 3.1–3.25 eV, depending on the synthetic temperature. These differences in properties affect the photocatalytic activities of the synthesized TiO2 nanoparticles.

A heterogeneous photocatalytic system is attracting much interest for water and air purification because of its reusability and economical advantage. Electrospun nanofibers are also receiving immense attention for efficient photocatalysts due to their ultra-high specific surface areas and aspect ratios. In this study, ZnO nanofibers with average diameters of 71, 151 and 168 nm are successfully synthesized by facile electrospinning and a subsequent calcination process at 500 ℃ for 3 h. Their crystal structures, morphology features and optical properties are systematically characterized by X-ray diffraction, scanning electron microscopy, UV-Vis and photoluminescence spectroscopies. The photocatalytic activities of the ZnO nanofibers are evaluated by the photodegradation of a rhodamine B aqueous solution. The results reveal that the diameter of the nanofiber, controlled by changing the polymer content in the precursor solution, plays an important role in the photocatalytic activities of the synthesized ZnO nanofibers.

Current synthesis processes for titanium dioxide (TiO2) nanoparticles require expensive precursors or templates as well as complex steps and long reaction times. In addition, these processes produce highly agglomerated nanoparticles. In this study, we demonstrate a simple and continuous approach to synthesize TiO2 nanoparticles by a salt-assisted ultrasonic spray pyrolysis method. We also investigate the effect of salt content in a precursor solution on the morphology and size of synthesized products. The synthesized TiO2 nanoparticles are systematically characterized by X-ray diffraction, transmission electron micrograph, and UV-Vis spectroscopy. These nanoparticles appear to have a single anatase phase and a uniform particle-size distribution with an average particle size of approximately 10 nm. By extrapolating the plots of the transformed Kubelka-Munk function versus the absorbed light energy, we determine that the energy band gap of the synthesized TiO2 nanoparticles is 3.25 eV

Despite numerous advances in the preparation and use of GaN, and many leading-edge applications in lighting technologies, the preparation of high-quality GaN powder remains a challenge. Ammonolytic preparations of polycrystalline GaN have been studied using various precursors, but all were time-consuming and required high temperatures. In this study, an efficient and low-temperature method to synthesize high-purity hexagonal GaN powder is developed using sub-micron Ga2O3 powder as a starting material. The sub-micron Ga2O3 powder was prepared by an ultrasonic spray pyrolysis process. The GaN powder is synthesized from the sub-micron Ga2O3 powder through a nitridation treatment in an NH3 flow at 800℃. The characteristics of the synthesized powder are systematically examined by X-ray diffraction, scanning and transmission electron microscopy, and UV-vis spectrophotometer.

곤충 머리의 부분 명칭들과 동소이명(同所異名)인 suture들의 명칭을 구조의 부분별 위치와 기능을 기준으로 하여 정리하고 우리말 이름들 을 체계적으로 모아서 조명하였다. 여기에는 머리 표면의 각종 선, 배자의 머리 구분, 머리의 외골격과 내골격, 입 내부구조, 긴주둥이, 더듬이 외부구조와 기본마디, 더듬이 모양, 표면 털 모양에 관한 용어들이 포함되어 있다.

PURPOSES: Seoul introduced public bicycles to reduce environmental pollution and create a healthy society. Because the use of bicycles is highly weather dependent, and bicycles are rented by the people, member characteristics and seasonal influences should be considered. This study analyzed bicycle traffic characteristics considering seasonal and member characteristics and highlighted some implications. METHODS: The Yeouido and Sangam districts, which have multiple business districts, were taken as the areas of interest. In order to reflect seasonal and membership characteristics, the traffic volume, time of use, and characteristics of each zone were categorized by season (spring, summer, autumn, winter) and membership type (season, daily, group). In addition, we analyzed the pattern of traffic volume and usage time according to the traffic purpose after separating rental locations into residential, business, subway, and park, reflecting the land characteristics. RESULTS: The results revealed that seasonal characteristics were high for bicycle traffic, time of use, and occupancy rate for park locations in spring and autumn. In terms of membership characteristics, group and daily users appeared as major visitors for park locations, and the trends of commuter pass users showed that bicycle use meets the purpose of introducing public bicycles. CONCLUSIONS: Traffic characteristics differed according to seasonal and membership characteristics. It is necessary to involve and extend the users of the commuter pass. Situations in which commuter pass users cannot function as a group or in which daily users monopolize bicycles (especially near parks, near subway stations, etc.) must be avoided.

PURPOSES: The effects on traffic accidents change with the changing environment. Accordingly, this study analyzes the characteristics of traffic accidents based on the personal characteristics (gender and age) of drivers, and those of 25 autonomous districts in Seoul, and suggests improvements. METHODS: Based on data pertaining to traffic accidents in Seoul, the analysis of accident characteristics was conducted by categorizing the types of traffic accidents according to the drivers' gender and age, and characteristics of 25 autonomous districts in Seoul. Further, for statistical verification, the SPSS software was used to derive influence variables through a multinomial logistic regression analysis, and a method for reducing traffic accidents was proposed. RESULTS : Analysis results show that males tend to be more involved in speed-related accidents and females in low-experience drivingrelated accidents such as those during parking and alleyway driving. In addition, variables such as age, automobile type, district, and day of the week are found to influence accident types. CONCLUSIONS : This study analyzed the accident characteristics based on personal and city characteristics to reflect the sociological characteristics that influence traffic accidents. The number of traffic accidents in Korea could be decreased drastically by implementing the results of this study in customized safety education and traffic maps.

곤충 머리에 있는 subgena (아랫뺨)와 clypeus (두순)는 연속된 피부판으로 통칭하여 peristome (입둘레판)으로 일컫는다. 따라서 subgenal sulcus (아랫뺨선)는 peristomal sulcus (입둘레홈) 또는 cranial-stomal sulcus (두개-입선)로 개정한다. 집파리류 성충 머리에 있는 ptilinal suture (이마주머니선)는 ptilinal fissure (얼굴주름)로 개정한다. 가슴에 있는 wing process (날개돌기)는 등판에 있는 것은 notal process (등판돌 기), 옆판에 있는 것은 pleural process (옆판돌기)로 각각 개정한다. 곤충 몸 아래쪽을 지칭하는 영역을 복부는 ventum (배판), 가슴은 sternum (가 슴판)으로 각각 지칭한다.

PURPOSES : The objective of this study is to develop a methodology to estimate the minimum required separation distance (MRSD) between a vehicle and a bicycle when overtaking.METHODS: Three steps have been conducted to develop a methodology to estimate MSRD. First, a literature review has been conducted on the measurement of MSRD, and how it may be applied in Korea. Second, two assumptions have been made to develop a methodology to estimate the MSRD. The first assumption is that the maximum separation distance between a vehicle and a bicycle can be observed when they are at the same location longitudinally. In addition, it is assumed that the separation distance is invalid when the contra-flow exists. Finally, three cameras were installed at a height of 10 m to record the vehicle-bicycle interaction. Moreover, the vehicle trajectories as well as the separation distance were coded and analyzed. Through the hypothesis test and the interval estimation, the sample mean was tested and the confidence interval was estimated.RESULTS : 141 records of separation distance data were collected, and the hypothesis test demonstrated that the MSRD in Korea is significantly higher than other countries. In addition, the confidence interval of the population mean of MSRD is from 1.51 m to 1.65 m with 95% level of confidence.CONCLUSIONS: It is expected that the proposed methodology to estimate MSRD would be beneficial in studying road safety of vehicles and bicycles. Also, the proposed MSRD is expected to be designated in the act of road and transportation.

The structural formation of inorganic nanoparticles dispersed in polymer matrices is a key technology for producing advanced nanocomposites with a unique combination of optical, electrical, and mechanical properties. Barium titanate (BaTiO3) nanoparticles are attractive for increasing the refractive index and dielectric constant of polymer nanocomposites. Current synthesis processes for BaTiO3 nanoparticles require expensive precursors or organic solvents, complicated steps, and long reaction times. In this study, we demonstrate a simple and continuous approach for synthesizing BaTiO3 nanoparticles based on a salt-assisted ultrasonic spray pyrolysis method. This process allows the synthesis of BaTiO3 nanoparticles with diameters of 20-50 nm and a highly crystalline tetragonal structure. The optical properties and photocatalytic activities of the nanoparticles show that they are suitable for use as fillers in various nanocomposites.

Photoelectron-hole separation efficiency plays an important role in the enhancement of the photocatalytic activity of photocatalysts towards the degradation of organic molecules. In this study, TiO2/TiOF2 heterostructured composite powders with suitable band structures, which structures are able to separate photoelectron-hole pairs, have been synthesized using a simple and versatile ultrasonic spray pyrolysis process. In addition, their phase volume fractions have been controlled by varying the pyrolysis temperature from 400 oC to 800 oC. The structural and optical properties of the synthesized powders have been characterized by X-ray diffraction, scanning electronic microscopy and UV-vis spectroscopy. The powder with a phase volume ratio close to 1, compared with single TiOF2 and other composite powders with different phase volume fractions, was found to have superior photocatalytic activity for the degradation of rhodamine B. This result shows that the TiO2/TiOF2 heterostructure promotes the separation of the photoinduced electrons and holes and that this powder can be applicable to environmental cleaning applications.

Inorganic phosphors based on ZrO2:Eu3+ nanoparticles were synthesized by a salt-assisted ultrasonic spray pyrolysis process that is suitable for industrially-scalable production because of its continuous nature and because it does not require expensive precursors, long reaction time, physical templates or surfactant. This facile process results in the formation of tiny, highly crystalline spherical nanoparticles without hard agglomeration. The powder X-ray diffraction patterns of the ZrO2:Eu3+ (1-20 mol%) confirmed the body centered tetragonal phase. The average particle size, estimated from the Scherrer equation and from TEM images, was found to be approximately 11 nm. Photoluminescence (PL) emission was recorded under 266 nm excitation and shows an intense emission peak at 607 nm, along with other emission peaks at 580, 592 and 632 nm which are indicated in red.