This paper aims to discuss the semantical　structure of coordinative compound words between Korean and Chinese. There are four kind of relations between the factors of coordinative words, that is overlapping, complementary, contiguous, inclined etc. Furthermore, in this paper we analysed the figurative meaning of coordinative words from cognitive linguistics. especially viewed from the metaphor and metonymy points. and analysed the reason of the figurative meaning of coordinative viewed from extension of meaning and semantic shift. Finally, we discussed the cultural connotation in the coordinative compound words from the social and psychological standard, the semantical compound words can reflect the same and different social culture features of Korea and China. Both Korea and China are seated east Asia, so there are so much same social culture. such as, 'male superiority' etc. We wish this paper will contribute to the study the relation of them.