In this study, it was developed eco-friendly zero cement fiber reinforced concrete using ground granulated blast furnace slag and alkali activator(water glass, sodium hydroxides). Also, it was evaluated the flexure capacity of the RC beams using zero cement concrete. The eco-friendly concrete using zero cement encouraged alkali activation reaction has rapid hardening speed and showed possibility as a high strength concrete. Also, the RC beams applied this showed similar movement and destroy tendency with RC used previous cement.