PURPOSES: An conventional method for electric power generation is converting thermal energy into mechanical energy then to electrical energy. Due to environmental issues such as global warming related with CO2 emission etc., were the limiting factor for the energy resources which resulting in extensive research and novel technologies are required to generate electric power. Thermal energy harvesting using thermoelectric generator is one of energy harvesting technologies due to diverse advantages for new green technology. This paper presents a possibility of application of the thermoelectric generator、s application in the direct exchange of waste solar energy into electrical power in road space. METHODS : To measure generated electric power of the thermoelectric generator, data logger was adopted as function of experimental factors such as using cooling sink, connection methods etc. Also, the thermoelectric generator、s behavior at low ambient temperature was investigated as measurement of output voltage vs. elapsed times. RESULTS: A few temperature difference between top an bottom of the thermoelectric generator is generated electric voltage. Components of an electrical circuit can be connected in various ways. The two simplest of these are called series and parallel and occur so open. Series shows slightly better performance in this study. An installation of cooling sink in the thermoelectric generator system was enhanced the output of power voltage. CONCLUSIONS : In this paper, a basic concepts of thermoelectric power generation is presented and applications of the thermoelectric generator to waste solar energy in road is estimated for green energy harvesting technology. The possibility of usage of thermoelectric technology for road facilities was found under the ambient thermal gradient between two surfaces of the thermoelectric module. An experiment results provide a testimony of the feasibility of the proposed environmental energy harvesting technology on the road facilities.