This study is to identify the effects of DRE (destruction and removal efficiency) and carbonization of Xylene when using the electron beam energy. The irradiation intensity of electron beam energy was 10 mA, 20 mA and irradiation time was 5.7, 11.4, 22.8, 45.6 sec (Absorbed dose are 41.41, 82.82, 165.64, 331.28, 662.55 kGy). The Xylene was completely removed at 331.28 kGy. Main by-products was carbon particles. Carbon particle formation was increased with irradiation intensity increasing. Most of the by-products of particle were Carbon black and Graphite.