Heavy metals are typical contaminant in water and need to be removed because they are non-biodegradable and can accumulate in human body. To remove metal and other contaminants from water, chemical absorbents are widely used due to their low cost. Herein, hybrid materials comprised of amylose and single wall carbon-nanotube (swCNT) was developed as the absorbent for water purification. A high adsorption properties of carbon-nanotubes have been utilized in designing effective absorbent but its poor dispersity in water is a limiting factor for practical use. Single wall carbon-nanotube was hybridized with amylose chain produced by enzyme reaction of amylosucrase and their tendency to self-assemble in aqueous environment. The amylose-swCNT microparticles were characterized by FE-SEM and turned out to be spherical structure with CNTs embedded throughout the amylose matrix. The ability of amylose-CNT microparticles to remove copper was examined. Concentration of copper was decreased after reaction with amylose-swCNT microparticles. Although amount of decreasing copper was less than swCNT on same total mass, Adsorption efficiency of amylose-swCNT microparticles was good because their swCNT content was only 10% of total mass.