In this study, we investigated to the heat transfer performance of coating nano-structure with various shapes and patterns on the heat transfer surface. As a result of the measurement of the 3D nano shape, it was confirmed that the roughness generally increases when the adhesive is sprayed on the coating surface and finished durability experiment. In the case of TEOS adhesive, the roughness increased by 0.074 ㎛, 0.012 ㎛ and 0.015 ㎛, and the contact angle decreased 12.64°, 1.31°, 9.84° at the coating time of 120 seconds, 180 seconds and 240 seconds, respectively. In the case of PVA adhesive, the roughness increased by 0.069 ㎛, 0.056 ㎛ and 0.03 ㎛, and the contact angle decreased 2.85°, 4.82°, 6.96° at the coating time of 120 seconds, 180 seconds and 240 seconds, respectively. In the case of DGEBF adhesive, the roughness increased by 0.042 ㎛, 0.053 ㎛ and 0 ㎛, and the contact angle decreased 0.81° at the coating time of 120 seconds, increased 4.82°, 6.96° at the coating time of 180 seconds and 240 seconds, respectively. As a result, the durability tends to decrease as more nano-structures are deposited, and 3D nano shapes, contact angles and SEM photographs showed that the performance of the PVA adhesive was superior among the three adhesives.