논문 상세보기
pp.27-35
The stability of liquid ferrate(Ⅵ) produced by an innovative method was confirmed and the degradation characteristics of cyclic compounds(Benzene, Aniline, Toluene, 1,4-Dioxane) by liquid ferrate(Ⅵ) were investigated under the same reaction conditions. When it was compared with the ferrate manufactured by the wet oxidation method, the liquid ferrate was more stable. And the stability of liquid ferrate was tested at the storage temperature. As a result, only 17.7% of liquid ferrate(Ⅵ) has decomposed at the storage temperature(4˚C) for 28 days. Among the cyclic compounds, the aniline was rapidly degraded compare to other cyclic compounds, which seems to be due to the electron-donating ability of the substituent, -NH2 group. Especially, when 1,4-dioxane was compared with benzene, the decomposition rate of 1,4-dioxane was lower than that of benzene, suggesting that oxygen atoms hinder the electrophilic reaction. Among 4 cyclic compounds, it was observed that aniline has the highest rate constant than those of other cyclic compounds.
1. 서 론
2. 재료 및 실험 방법
2.1 재료
2.2 실험 방법
3. 결과 및 고찰
3.1 Ferrate(Ⅵ)
3.2 방향족 화합물의 분해 특성 비교
3.3 Benzene과 1,4-Dioxane의 분해 특성 비교
3.4 반응속도
4. 결 론
사 사
References
