Zeolite 4A was synthesized by fusion method from coal fly ash discharged at the thermal power plants. The synthesized zeolite(FAZ) was characterized through particle size analyzer, XRD, XRF and SEM. N2 adsorption-desorption measurement was used to examine surface and pore structures. The adsorption experiments were carried out under dynamic conditions of trace SO2 in N2 to investigate SO2 adsorption capacity of FAZ. The experiments were conducted to characterize the breakthrough characteristics of SO2 in a fixed bed under different operating conditions including temperature(50-125℃), concentration of SO2(3000-10000 ppm) and FAZ with 4 kinds of commercial zeolite. The adsorption capacity of FAZ was 53.84 mgSO2/g adsorbent, larger than that of the same type commercial zeolite(WK4A).