This study was conducted to investigate the treatment of wastewater from acetaldehyde manufacturing plant by activated sludge process with Micrococcus roseus AW-6, Micrococcus luteus AW-22, Microbacterium lacticum AW-38 and Microbacterium laevaniformans AW-41. The COD_Mn and BOD_5 of the wastewater were 5,260㎎/L and 6,452㎎/L, respectively. pH was 1.85. The main organic component in the wastewater was acetic acid which was contained 67,600㎎/L. Optimum dilution time for activated sludge process was shown 10 times. The specific substrate removal rate(K_e) was 1.95day^-1 and the nonbiodegradable matters(S_n) were 23.2㎎/L. Saturation constant (K_e) and maximum specific growth rate(q_max) were 1,640㎎/L and 2.33day^-1, respectively. Sludge yield coefficient(Y) and endogenous respiration coefficient(K_d) were 0.28㎎ MLVSS/㎎COD and 0.02day^-1, respectively. COD_cr removal efficiency was 91% for 1.95day of hydraulic retention time.
Permethrin[3-phenoxybenzyl (1RS)-cis,trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane carboxylatel insecticides were selected to study adsorption and leaching potentials related to pollution on Commerce silty clay loam soil near Baton Rouge, Louisiana, USA. GLC-ECD chromatogram of permethrin included 32.5 % of cis-permethrin and 67.4 % of trans-permethrin. Extraction efficiencies of cis and trans-permethrin were 92.5 % and 92.3 in fortified water, respectively and 85.9 % and 88.8 % in fortified soil, respectively. At a 1:10 soil/water ratio,the Koc values for cis and trans isomers of permethrin were 938 and 877, respectively. Leaching of permethrin was evaluated in soil columns(5.4 cm i.d. × 26 cm length). Total recoveries of the permethrin applied to the soil column were 84.5 ± 3.1 %. When the soil columns were leached with three pore volumes of water, the distributions of cis-permethrin leached were 6.10 % and 0.07 % of amount applied in the untreated zone soil and leachate water, respectively. Trans-permethrin distributions were 5.20 % in the untreated zone soil and 0.05 % in leachate water. Cis and trans-permethrin was strongly adsorbed to soil. The results of the study showed the strong relationship between adsorption and leaching. Cis and trans-permethrin to be leached into the groundwater in soils with shallow aquifers were suggested a low leaching potential.
PCBs have been measured using GC-ECD, GC-MS, GC-ELCD, HPLC, TLC, NMR and Immunoassay. The analysis of PCBs using GC- ECD include the peak pattern method as none derivatization and the perchlorination method as derivatization. This study was conducted to establish the perchlorination method with SbCl_5 from PCBs to decachlorinated biphenyl(DCB). The aroclor 1242 of PCBs was chlorinated and then, converted into the DCB which showed a single peak in GC-ECD chromatogram. The detection limit of DCB was 2pg. The quantification detection concentration of PCBs extracted with soxhlet was 0.5ng/g in the soil. PCBs were not detected in the suburban soil, but 174ng/g in the soil of industrial complex. Mean PCBs concentration of Shinchun stream at Kumho river and Jinchun stream at Nakdong river was calculated average 88ng/g in the sediment. PCBs concentration in the sediment of Kumho river near 2-7㎞ from conjunction with Nakdong river was average 154ng/g. PCBs concentration in the sediment of Nakdong river near conjunction with Kumho river was average 159ng/g.