Electricity generation through fossil fuels has caused environmental pollution. To solve this problem, research on new renewable energy (solar, wind, geothermal heat, etc.) to replace fossil fuels is in progress. These devices are able to consistently generate power. However, they have many drawbacks, such as high installation costs and limitations in possible set-up environments. Thus, piezoelectric harvesting technology, which is able to overcome the limitations of existing energy technologies, is actively being studied. Piezoelectric harvesting technology uses the piezoelectric effect which occurs in crystals that generate voltage when stress is applied. Therefore, it has advantages such as a wider installation base and lower technological cost. In this study, a piezoelectric energy harvesting device based on constant wave motion was investigated. This device can regenerate electricity in a constant turbulent flow in the middle of the sea. The components of the device are circuitry, a steel bar, an bimorph piezoelectric element and buoyancy elements. In addition, a multiphysical analysis coupled with the structure and piezoelectric elements was conducted to estimate the performance of the device. With this piezoelectric energy harvesting device, the displacement and electric power were analyzed.

The absorption spectra of synthesis of long chain fatty acid containing azobenzene start from p-(p'-hydroxy phenyl azo)-benzoic acid was investigated by ultraviolet spectrophotometery in chloroform solvent at the various temperature. In addition, The pressure-area of the water-air interface was obtained and the LB film was fabricated onto a quartz slide and quartz crystal by conventional Langmuir-Blodgett(LB) method. The UV absorption spectra of Langmuir-Blodgett(LB) film on quartz slide and spectrum of monolayer formed on quartz crystal have been measured. Long chain fatty acid containing azobenzene are induced phtoisomerization by the application of u. v. and visible light irradiation alternatively the reversibility of phtoisomerization was more clear difference when the number of Cn increased but, not so good at C14-azo. At the pressure-area isotherms, the value of surface pressure increment were decreased when the number of Cn increased. A surface pressure of 20mN/m was obtained as a proper one for a film deposition. The photoisomerization at LB films were induced by application of UV and visible light irradiation alternatively. So the LB film of long chain fatty acid containing azobenzene has possibility to being applied to functional molecular devices such as photomemory and light switching.

The Synthesis of long chain fatty acid containing azobenzene and (Cn-Azo) was optimized, starting from p-(p'-hydroxy phenyl azo)-benzoic acid and the product of reaction containing azobenzene chromophores was investigated by ultraviolet spectrophotometery in chloroform solvent at the various temperature. In addition, Reversibility and stability of azo compounds have been measured by means of Ultraviolet and the structure of these compound were ascertained by means of FT-IR and NMR. Recrystallization of reaction product in the solvent results the experimental yield obtained about 62.93% p-(p'-octadecyloxy phenyl azo)-benzoic acid. Long chain azobenzene derivatives in chloroform solution are induced photoisomerization by u. v. and visible light irradiation. The solution of long chain fatty acids(Cn-Azo) containing azobenzene are possible of being applied to functional molecular devices such as photomemory and light switching.