This work investigates the relationship between the sea breeze circulation and ozone concentrations during cold water events in the southeastern coastal area of the Korean Peninsula, where coastal upwelling frequently occur. This analysis was performed based on the classification of two categories, such as cold water and non-cold water events, over the period of 2000-2009. The low air temperature (0.5℃), low SST (5℃) and the wind direction(southerly) are the features of the cold water events in the Southeastern coastal area. Moreover, ozone concentrations in the cases of the sea breeze circulation and cold water events were significantly lower (below 30 ppb) than those (70∼100 ppb) in the non-clod water events, because of the low air temperature (10∼20℃) and high wind speed (3∼5 m/s) around the southeastern coastal area.

In order to clarify the relation between sea breeze penetration and Planetary Boundary Layer development in southeastern part of the Korean Peninsula, several numerical assessments were carried out using atmospheric numerical model WRF(Weather Research and Forecasting). Compared with onset time of sea breeze at eastern coast area(Uljin), the time at southern coast region(Masan) with complex costal line tend to delay for several hours. The penetration patterns of sea breeze between two coastal regions are some different due to the shape of their coastal line and back ground topography. Intensified valley wind due to high topography of lee side of Uljin can help penetration of sea breeze at early time. So penetration of sea breeze at early time often prevent PBL to develop at Uljin and lower PBL height last for a day time. But because of late penetration of sea breeze at Masna, PBL Height dramatically decrease after 1500LST. The distribution of front genesis function based on the heat and momentum variation are explained obviously the sea breeze penetration patterns and agreed well with the PBL height distribution.

Numerical simulation is essential to indicate the flow of the atmosphere in the region with a complicated topography which consists of many mountains in the inland while it is neighboring the seashore. Such complicated topography produces land and sea breeze as the mesoscale phenomenon of meteorology which results from the effect of the sea and inland. In the mesoscale simulation examines, the change of the temperature in relation to the one of the sea surface for the boundary condition and, in the inland, the interaction between the atmosphere and land surface reflecting the characteristic of the land surface. This research developed and simulated PNULSM to reflect both the SST and vegetation effect as a bottom boundary for detailed meteorological numerical simulation in coastal urban area. The result from four experiments performed according to this protocol revealed the change of temperature field and wind field depending on each effect. Therefore, the lower level of establishment of bottom boundary suitable for the characteristic of the region is necessary to figure out the atmospheric flow more precisely, and if the characteristic of the surface is improved to more realistic conditions, it will facilitate the simulation of regional environment.

In this study, climate analysis and wind sector division were conducted for a propriety assessment to determine the location of air quality monitoring sites in the Busan metropolitan area. The results based on the meteorological data(2000～2004) indicated hat air temperature is strongly correlated between 9 atmospheric monitoring sites, while wind speed and direction are not. This is because wind is strongly affected by the surrounding terrain and the obstacles such as building and tree. In the next stage, we performed cluster analysis to divide wind sector over the Busan metropolitan area. The cluster analysis showed that the Busan metropolitan area is divided into 6 wind sectors. However 1 downtown and 2 suburbs an area covering significantly broad region in Busan are not divided into independent sectors, because of the absence of atmospheric monitoring site. As such, the Busan metropolitan area is finally divided into 9 sectors.