Wrought Si-steels are generally used for electromagnetic valves, which are needed good response. To date, Hitachi Powdered Metals Co., Ltd. have produced Fe-Si base sintered magnetic material, EU-52, which shows a magnetic flux density of more than 1.25T at 2000A/m and a maximum permeability of more than 3500. However these magnetic properties are lower than that of wrought Si-steels. Because EU-52 has a low density of 7.2Mg/m3. For improving the magnetic properties, it is necessary to increase the density of sintered cores. To increase density, a new mixing method of coating fine Si powders on atomized iron powders was developed, for avoiding the Kirkendall effect. As the result, developed P/M Fe-Si magnetic cores shows higher density of 7.38Mg/m3, higher magnetic flux density of 1.48T at 2000A/m and higher maximum permeability of 6800.