In this investigation, samples of the chemical (Hg1-xPbxBa2Ca1.8Mg0.2Cu3O8+δ) were prepared utilizing a solid-state reaction technique with a range of lead concentrations (x = 0.0, 0.05, 0.10, and 0.20). Specimens were pressed at 8 tons per square centimeter and then prepared at 1,138 K in the furnace. The crystalline structure and surface topography of all samples were examined using X-ray diffraction (XRD) and atomic force microscopy (AFM). X-ray diffraction results showed that all of the prepared samples had a tetragonal crystal structure. Also, the results showed that when lead was partially replaced with mercury, an increase in the lead value impacted the phase ratio, and lattice parameter values. The AFM results likewise showed excellent crystalline consistency and remarkable homogeneity during processing. The electrical resistivity was calculated as a function of temperature, and the results showed that all samples had a contagious behavior, as the resistivity decreased with decreasing temperature. The critical temperature was calculated and found to change, from 102, 96, 107, and 119 K, when increasing the lead values in the samples from 0.0 to 0.05, 0.10, and 0.20, respectively.
An eco-friendly material was synthesized through interfacial polymerization of aniline on particles of g-C3N4 with arginine, resulting in Arg-PANI@g-C3N4 composite. The as-synthesized composite was characterized by the Brunauer, Emmett, and Teller (BET) surface area, X-ray energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-ray diffraction (XRD). The adsorption capability of as-synthesized composite towards Orange G (OG) dye has been evaluated under several experimental conditions, such as the adsorbent dosage, initial dye concentration, contact time under agitation, pH of dye solution and temperature. Thermodynamics parameters such as free energy (ΔG°), entropy (ΔS°), and enthalpy (ΔH°) were also calculated and suggested that the adsorption process is spontaneous and endothermic in nature. The kinetics data revealed that the adsorption of OG dye onto Arg-PANI@g-C3N4 follows the pseudo-second order kinetics model. The maximum adsorption capacity was found to be 80.54 mg·g−1. Furthermore, the Arg-PANI@g-C3N4 surface exhibited a Langmuir-like adsorption isotherm in contrast to a Freundlich isotherm due to homogeneous active site distribution. Regeneration investigation showed the excellent reusability of Arg-PANI@g-C3N4 composite during the cleaning up of solution containing OG dye molecules.
Lignocellulosic materials such as agricultural residues have been identified as potential sustainable sources that can replace petroleum-based polymers. This study focused on the conversion of lignin extracted from bagasse to carbon fiber (CF) and cellulose nanocrystal (CNC). The highest extraction of lignin yield was achieved at 100 °C using 10% NaOH for 12 h. Carbon fibers were obtained by electro-spinning of bagasse lignin blended with polyvinyl alcohol (PVA) (11 wt/v %) followed by thermo-stabilization (250 °C) in an oxidizing atmosphere and further carbonization in an inert atmosphere (850 °C). Conventional hydrolysis process was used to extract cellulose nanocrystal from bagasse pulp. Morphological (scanning electron microscopy, SEM), spectral (Fourier transform infrared, FTIR) spectroscopy, elemental analysis, thermal characterization and surface area measurements have been carried out. Figures originated by SEM showed that CF ranges from 145 to 204 nm, while stabilized bagasse cellulose nanocrystal (SCNC) appeared as rod-shape like structure in the range of length 600–800 nm and diameter 5.33–19 μm. Characterization results revealed that CF exhibits microporous structure, while bagasse lignin and SCNC display mesoporous structure. In addition, the results proved that SCNC exhibits a percentage removal 71.56% for methylene blue dye in an aqueous solution.
Self-defence has long been understood as an inherent right of a State when it is militarily attacked by another State. After September 11 attacks, however, there have been attempts to reinterpret the meaning of ‘armed attack’ under Article 51 of the UN Charter to include attacks by terrorists - non-State actors. This paper critically examines the legal and policy considerations that promote a right of self-defence against terrorists by means of thoroughly analyzing the text of the UN Charter, State practice and the jurisprudence of the ICJ. The paper finds that a terrorist attack as such may not be an armed attack within the meaning of Article 51 of the Charter unless it is an act of a State or directly imputable to a State and is on a large scale with substantial effects. The paper concludes that unilateral use of force against a State in the name of self-defence is not the correct way of combating terrorism and that there are effective alternatives such as addressing the root causes of terrorism, resorting to law enforcement mechanisms or coercive countermeasures, and strengthening multilateralism.
Islamic international law is a branch of the Shari’ah (Islamic law). Due to the classical doctrine of the notion of‘ Jihad,’there have been misconceptions and Islam has been painted as a religion encouraging violence and war. This paper appeals for the reconsideration of the classical doctrine, which was adopted at a time when there was a state of war between Islamic and non-Islamic states. Going back to the roots and referring to the Qur’an and the Sunnah: the two primary sources of Islamic law, the paper argues that Islam prohibits aggressive war and that the essence of‘ jihad’ is‘ self-defense.’After elaborating the essential conditions of the right of self-defense, the paper concludes that Islamic international law can contribute much to the present world order by providing moral and ethical values that modern international law is lacking.
This study contributes to the existing literature by empirically exploring the causes of child labor in the Indonesian labor market. Factors identified include rate of poverty, average wages, education participation, and quality of education. This study utilized an aggregate data of 301 districts and cities across 34 provinces sourced from the National Labor Force Survey and the National School/Madrasah Accreditation Board of the Republic of Indonesia. Using a multiple regression analysis, the study found strong evidence of the positive effect of poverty on child labor. Conversely, the study documented the adverse impact of average wages on child labor in Indonesia. Similarly, the participation in the education system also contributed negatively to the child labor. Finally, the quality of education services is found to have a negative effect on child labor in Indonesia. The findings of this study suggest that, in efforts to reduce the involvement of children in the workforce, the poverty eradication program should be enhanced. The wages should be continuously improved, at least, in par with the changes in prices. Finally, the quality of education and its services ought to be further enhanced to attract more child student participation rates across junior high schools nationwide.