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        검색결과 6

        1.
        2023.05 구독 인증기관·개인회원 무료
        In molten salt reactor (MSR), liquid fuel integrated with the molten salt coolant is used to improve the safety, resulting in the prevention of the loss-of-coolant accident (LOCA) that can occur in a pressurized water reactor (PWR). Because the structural materials used in MSRs are directly contacted with liquid fuel for a long time, they must have excellent corrosion resistance to the molten salt. Therefore, to examine the corrosion rates for Ni-based alloys in the molten salt, the corrosion experiments for alloy 600, alloy 617, and Hastelloy N were performed under LiCl molten salt at 635°C for 100 h in a glove box under Ar environment. Through a weight loss method for the three Nibased coupons before and after the corrosion tests, we evaluated their corrosion rates. Based on the results of weight loss for each alloy, we confirmed that Hastelloy N has the excellent corrosion resistance compared to the other alloys. Furthermore, the changes in the crystal structure and surface morphology with elemental distribution for the three alloys by corrosion in LiCl molten salt were analyzed, showing the variation in surface topography and the decrease in Cr element after corrosion experiments for all coupons.
        2.
        2022.05 KCI 등재 SCOPUS 구독 인증기관 무료, 개인회원 유료
        Designing and producing a low-cost, high-current-density electrode with good electrocatalytic activity for the oxygen evolution reaction (OER) is still a major challenge for the industrial hydrogen energy economy. In this study, nanostructured Fe-doped CuCo(OH)2 was discovered to be a precedent electrocatalyst for OER with low overpotential, low Tafel slope, good durability, and high electrochemically active surface sites at reduced mass loadings. Fe-doped CuCo(OH)2 nanosheets are made using a hydrothermal synthesis process. These nanosheets are clumped together to form a highly open hierarchical structure. When used as an electrocatalyst, the Fe-doped CuCo(OH)2 nanosheets required an overpotential of 260 mV to reach a current density of 50 mA cm−2. Also, it showed a small Tafel slope of 72.9 mV dec−1, and superior stability while catalyzing the generation of O2 continuously for 20 hours. The Fe-doped CuCo(OH)2 was found to have a large number of active sites which provide hierarchical and stable transfer routes for both electrolyte ions and electrons, resulting in exceptional OER performance.
        4,000원
        5.
        2020.05 KCI 등재 SCOPUS 구독 인증기관 무료, 개인회원 유료
        The design and fabrication of catalysts with low-cost and high electrocatalytic activity for the oxygen evolution reaction (OER) have remained challenging because of the sluggish kinetics of this reaction. The key to the pursuit of efficient electrocatalysts is to design them with high surface area and more active sites. In this work, we have successfully synthesized a highly stable and active NiCo2S4 nanowire array on a Ni-foam substrate (NiCo2S4 NW/NF) via a two-step hydrothermal synthesis approach. This NiCo2S4 NW/NF exhibits overpotential as low as 275 mV, delivering a current density of 20 mA cm-2 (versus reversible hydrogen electrode) with a low Tafel slope of 89 mV dec-1 and superior long-term stability for 20 h in 1M KOH electrolyte. The outstanding performance is ascribed to the inherent activity of the binder-free deposited, vertically aligned nanowire structure, which provides a large number of electrochemically active surface sites, accelerating electron transfer, and simultaneously enhancing the diffusion of electrolyte.
        4,000원
        6.
        2018.04 KCI 등재 서비스 종료(열람 제한)
        흡연 유무의 남성을 대상으로 뇌 회백질의 손상 유무를 파악 할 수 있는 확산텐서영상을 검사하여 영상을 획득 한 후 Tract-Based Spatial Statics(TBSS)방법으로 뇌 회백질 부위의 기저핵 신경섬유로의 비등방도 FA(fractional anisotropy)값을 측정 분석한 결과 모든 영역에서 흡연자가 비흡연자보다 비등방성 측정값이 낮게 관찰되었으며 FA값은 통계적으로 유의하였다. 본 연구의 측정한 FA결과 값으로 추측하자면 즉, 흡연이 뇌 회백질 기저핵의 모든 해부학적 미세 구조성 변화에 크게 영향을 미치며 신경 섬유로를 손상시키고 이와 관련된 기능적 이상에 영향을 준다고 할 수 있다.