Modification of the surface of raw activated carbon using chemical solvents can significantly improve the adsorption performance of activated carbon. Triethylenetetramine is one of the most important chemical solvents used to modify raw activated carbon for formaldehyde removal indoor. We conducted the liquid impregnation experiments at different initial concentrations, temperatures, adsorbent dosage and time ranges to fully investigate the adsorption of triethylenetetramine on the surface of raw activated carbon for modification. We found that the Langmuir isotherm model and pseudo-first-order kinetic model fit quite well with the experimental data and the R2 are 0.9883 and 0.9954, respectively. The theoretical maximum adsorption capacity is 166.67 mg/g. The change in Gibbs free energy (ΔG0), enthalpy change (ΔH0) and entropy change (ΔS0) were also calculated to study the direction and driving force of the liquid adsorption process. In order to understand the adsorption process at the molecular level, a new activated carbon model based on the actual physical and chemical properties of activated carbon was carefully established in the Materials Studio to simulate the liquid-phase adsorption. The pore structure, elemental composition, functional group content, density, pore volume, and porosity of the activated carbon model converge close to the actual activated carbon and the adsorption isotherms obtained from the simulation agree well with the experimental results. The results show that the adsorption of triethylenetetramine on activated carbon is a spontaneous, endothermic and monolayer physical adsorption process.
Multiwall carbon nanotubes (MWCNT) with two different (L/D) aspect ratios (7±2 μm/140±30 nm and 0.5–2 μm/8–15 nm) were surface treated using nitric acid (HNO3) and polyethyleneimine (PEI) prior to their deposition on carbon fibers (CF). Before the hierarchical reinforcement with CF-MWCNT, the CFs were treated with 3-glycidoxypropyltrimethoxysilane, a coupling agent (Z6040) and with poly(amidoamine) (PAMAM) a dendrimer containing an ethylenediamine core and amine surface groups. The MWCNT were deposited on the CF using two methods, by electrostatic attraction and by chemical reactions. The changes in the CF surface morphology after the MWCNT deposition were analyzed using SEM, which revealed a higher density and uniform coverage for the PAMAM-treated CF and the short MWCNTs. The interfacial adhesion of the composite materials was evaluated using the single fiber fragmentation technique. The results indicated an improvement in the interfacial shear strength with the addition of the short-MWCNTs treated with acid solutions and grafted onto the surface of the CF fiber using electrostatic attraction.
We present a summary of our spectroscopic redshift catalogue of 404 sources in the AKARI Deep Field South (ADF-S). We have used the AAOmega spectrograph to target mid-infrared and far-infrared sources selected primarily from AKARI observations in this field for which we were able to obtain optical counterparts. Our sources with identified redshifts include 316 with Hα detections at z 0:345 and 15 sources at z > 1 with MgII or Ly emission lines. About 13% of our z 0:345 sources are dominated by active galactic nuclei (AGN) emission, although many show emission from both star formation and AGNs. The median Balmer decrement is 5.9. Ultra-luminous infrared galaxies (ULIRGs) were found only in the higher-redshift sources. Optical and near infrared data will be available shortly, enabling calibration of the line luminosities and spectral energy distribution (SED) tting for these sources.
How does the presence of an AGN in uence the total SFR estimates of galaxies and change their distribution with respect to the Galaxy Main Sequence? To contribute to solving this question, we study a sample of 1133 sources detected in the North Ecliptic Pole field (NEP) by AKARI and Herschel. We create a multi-wavelength dataset for these galaxies and we fit their multi-wavelength Spectral Energy Distribution (SED) using the whole spectral regime (from 0.1 to 500 μm). We perform the fit using three procedures: LePhare and two optimised codes for identifying AGN tracers from the SED analysis. In this work we present an overview of the comparison between the estimates of the Infrared bolometric luminosi- ties (between 8 and 1000 μm) and the AGN fractions obtained exploiting these dierent procedures. In particular, by estimating the AGN contribution in four different wavelength ranges (5-40 μm, 10-20 μm, 20-40 μm and 8-1000 μm) we show how the presence of an AGN affects the PAH emission by suppressing the ratio L8 μm L4:5 μm as a function of the considered wavelength range.
The preliminary data reduction, analysis and first results from the Herschel survey of the AKARI NEP field are presented. Herschel SPIRE observations of the NEP-Wide region and PACS observations of the NEP-Deep region have yielded galaxy catalogues of 4000 and 900 sources respectively down to ux density levels of approximately 15 mJy at 100-250 microns. Source counts produced from these catalogues reach cosmologically significant depths tracing the evolutionary upturn and turnover in the source counts. The source counts are in agreement with other large area surveys carried out with Herschel bridging the gap between the shallow and deep Herschel surveys.
A full-scale process has been developed to immobilize fission products that accumulate within the Mark IV electrorefiner (ER) electrolyte at Idaho National Laboratory. ER salt was blended with treatment additives, followed by pressureless consolidation (PC) in a furnace to produce a durable ceramic waste form (CWF). The goal is the development of a process to consolidate actual radioactive ER salt into a form suitable for transportation and disposal.Four batches (300 to 400 kg per batch) of full-scale pre-qualification material preparation runs have been prepared. From these four batches of nonradioactive salt-loaded surrogate material, three full-scale PC trials have been conducted. The first PC test run, established equipment parameters with a basic CWF container design. The second trial included a modified CWF container design, real-time measurement of CWF consolidation, and an audio recording to identify cracking during the CWF cool-down. During the third trial, salt was doped (from the fourth material preparation batch) to create a nonradioactive salt material and to more closely represent actual ER salt. The second and third trials were also used to validate a model developed for the CWF. The CWF model is beneficial for understanding and predicting the physical processes that occur during the heat cycle. This would be particularly useful when the CWF is located in a hot cell, which makes accessing and examining a CWF difficult.
Polarbear is a ground-based experiment located in the Atacama desert of northern Chile. The experiment is designed to measure the Cosmic Microwave Background B-mode polarization at several arcminute resolution. The CMB B-mode polarization on degree angular scales is a unique signature of primordial gravitational waves from cosmic in ation and B-mode signal on sub-degree scales is induced by the gravitational lensing from large-scale structure. Science observations began in early 2012 with an array of 1,274 polarization sensitive antenna-couple Transition Edge Sensor (TES) bolometers at 150 GHz. We published the first CMB-only measurement of the B-mode polarization on sub-degree scales induced by gravitational lensing in December 2013 followed by the first measurement of the B-mode power spectrum on those scales in March 2014. In this proceedings, we review the physics of CMB B-modes and then describe the Polarbear experiment, observations, and recent results.
The Eclipsing Binaries Minima (BIMA) Monitoring Project is a CCD-based photometric observational program initiated by Bosscha Observatory - Lembang, Indonesia in June 2012. Since December 2012 the National Astronomical Research Institute of Thailand (NARIT) has joined the BIMA Project as the main partner. This project aims to build an open-database of eclipsing binary minima and to establish the orbital period of each system and its variations. The project is conducted on the basis of multisite monitoring observations of eclipsing binaries with magnitudes less than 19 mag. Dierential photometry methods have been applied throughout the observations. Data reduction was performed using IRAF. The observations were carried out in BVRI bands using three dierent small telescopes situated in Indonesia, Thailand, and Chile. Computer programs have been developed for calculating the time of minima. To date, more than 140 eclipsing binaries have been observed. From them 71 minima have been determined. We present and discuss the O-C diagrams for some eclipsing binary systems.
Prior research has investigated the consumer effects of cash and card payments in service settings, but the growing trend of innovative payment with a mobile device hasn’t been considered in the literature so fare. This article represents one of the first studies that considers the adoption of mobile as a new payment method and investigate how the ‘checkout’ phase affect the shoppers’ overall price image of retail stores (OSPI). Results from our studies show that the ‘checkout’ phase is the ‘moment of truth’ for shoppers judging OSPI. We investigate the effects of cash, card, and mobile payments and show that the less transparent a payment method, the lower OSPI judgments of shoppers. In particular, favorable comparisons of basket prices to shoppers’ mental budgets trigger lower store price perceptions. Subsequently, these results have major implications for retailers aiming to lower their OSPI in customers’ minds.