To ensure the safety of disposal facilities for radioactive waste, it is essential to quantitatively evaluate the performance of the waste disposal facilities by using safety assessment models. This paper addresses the development of the safety assessment model for the underground silo of Wolseong Low-and Immediate-Level Waste (LILW) disposal facility in Korea. As the simulated result, the nuclides diffused from the waste were kept inside the silo without the leakage of those while the integrity of the concrete is maintained. After the degradation of concrete, radionuclides migrate in the same direction as the groundwater flow by mainly advection mechanism. The release of radionuclides has a positive linear relationship with a half-life in the range of medium half-life. Additionally, the solidified waste form delays and reduces the migration of radionuclides through the interaction between the nuclides and the solidified medium. Herein, the phenomenon of this delay was implemented with the mass transfer coefficient of the flux node at numerical modeling. The solidification effects, which are delaying and reducing the leakage of nuclides, were maintained the integrity of the nuclides. This effect was decreased by increasing the half-life and the mass transfer coefficient of radionuclides.

The organic complexing agents such as ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), and isosaccharinic acid (ISA) can enhance the radionuclides’ solubility and have the potential to induce the acceleration of radionuclides’ mobility to a far-field from the radioactive waste repository. Hence, it is essential to evaluate the effect of organic complexing agents on radionuclide solubility through experimental analysis under similar conditions to those at the radioactive waste disposal site. In this study, five radionuclides (cesium, cobalt, strontium, iodine, and uranium) and three organic complexing agents (EDTA, NTA, and ISA) were selected as model substances. To simulate environmental conditions, the groundwater was collected near the repository and applied for solubility experiments. The solubility experiments were carried out under various ranges of pHs (7, 9, 11, and 13), temperatures (10°C, 20°C, and 40°C), and concentrations of organic complexing agents (0, 10-5, 10-4, 10-3, and 10-2 M). Experimental results showed that the presence of organic complexing agents significantly increased the solubility of the radionuclides. Cobalt and strontium had high solubility enhancement factors, even at low concentrations of organic complexing agents. We also developed a support vector machine (SVM) model using some of the experimental data and validated it using the rest of the solubility data. The root mean square error (RMSE) in the training and validation sets was 0.012 and 0.016, respectively. The SVM model allowed us to estimate the solubility value under untested conditions (e.g., pH 12, temperature 30°C, ISA 5×10-4 M). Therefore, our experimental solubility data and the SVM model can be used to predict radionuclide solubility and solubility enhancement by organic complexing agents under various conditions.

Radioactive waste containing cellulosic materials such as cotton, paper and wood are being disposed in Low-and intermediate-level radioactive waste disposal site in Gyeongju. Cellulose has recently emerged great issue in terms of disposal site safety as it can be decomposed into an organic complex compound, ISA (isosaccharinic acid), under strong alkali conditions (pH 12.5 or higher) formed by the hydrated cement, to accelerate the mobility of the radionuclides in the disposal facility. However, in Korea, there are insufficient criteria for confirming the suitability for disposal of low-and intermediatelevel radioactive wastes including cellulose, and there is no specific method for evaluating the total amount of waste to confirm the suitability of disposal. Therefore, the method of SKB (Swedish Nuclear and Fuel Management Company), which has established acceptance criteria related to the physicalchemistry safety of cellulose, is analyzed to suggest a method for deriving the amount of cellulosecontaining waste disposal. Cellulose, an organic complexing agent, is an important consideration for safety case at the Swedish low-and intermediate-level radioactive waste disposal site SFR. SKB calculated the amount of cellulose generated by separately labeling cellulose-containing wastes of 1-2BMA, Silo and 1BTF (SKB 2013). BLA, a low-level radioactive waste disposal facility, is not considered due to its low radionuclide inventory (~0.2% of SFR’s total radionuclide inventory, SKB 2013). To calculate the amount of cellulose that can be disposed of, information on the mass and volume of hydrated cement (concrete waste, cement solidification waste, disposal container, grouting, disposal shed), the concentration of ISA absorbed in the hydrated cement, and the concentration of ISA dissolved in the groundwater which were used. In addition, the total disposable amount was calculated using the cellulose degradation rate, composition ratio, and the cellulose containing waste volume.

Cellulose-based wastes can be degraded into short-chain organic acids at the cementitious radioactive waste repository. Isosaccharinic acid (ISA), one of the main degradation products, can form the chelate complex with metals and radionuclides, and these complexes have a potential that can accelerate to move the radionuclides to far-field from the repository. This study characterized the amount of generated ISA from typical cellulosic materials in the repository. Two different degradation experiments were conducted under alkaline conditions (saturated with Ca(OH)2 at pH 12.4): i) cellulosic material mixture under an opened condition (partially aerobic), and ii) cellulosic material under an anaerobic condition in a nitrogen-purged glove box. In the first case, three different types of cellulosic materials–paper, cotton, and wood– were mixed at the same ratio, and the experiments were carried out at three different temperatures (20°C, 40°C, and 60°C). It revealed that both the cellulose degradation rate and generated ISA concentration were high at high reaction temperatures, and various soluble degradation products such as formic acid and lactic acid were generated. The cellulose degradation in this work seems to still stay at a peeling-off process. In the second study, each type of cellulosic material was applied in its own batch experiments, and the amount of generated ISA was in the order of paper > wood > cotton. The above two experiments are supposed to be a long-term study until the generated ISA reaches an equilibrium state.

To obtain confidence in the safety of disposal facilities for radioactive waste, it is essential to quantitatively evaluate the performance of the waste disposal facilities by using safety assessment models. Thus, safety assessment models require uncertainty management as a key part of the confidencebuilding process. In application to the numerical modelling, the global sensitivity analysis is widely employed for dealing with parametric and conceptual uncertainties. In particular, the parametric uncertainty can be effectively reduced by minimizing the uncertainty of critical parameters in the safety assessment model. In this paper, the numerical model of each step disposal facility (Silo, Near surface, and Trench type) at Wolsong Low and Immediate Level Waste (LILW) Disposal Center is designed by using a two-dimensional finite element code (COMSOL Multiphysics). In order to determine the critical parameters for non-adsorbed nuclides such as H-3, C-14, Tc-99, we introduced the variance-based sensitivity analysis methodology of the global sensitivity analysis. In the case of Silo type, the density of waste is highly sensitive to the total leakage quantity of all nuclides. Additionally, the initial nuclide concentration of H-3 was identified as another important parameter of H-3. On the other hands, the mass transport coefficient showed a high contribution in C-14 and Tc-99. In other types of disposal facilities, the leaking properties of H-3 are significantly affected by the amount of infiltration water. However, C-14 and Tc-99 were found to be more sensitive to the density of waste.

Numerical model was developed that simulates radionuclide (3 H and 14C) transport modeling at the 2nd phase facility at the Wolsong LILW Disposal Center. Four scenarios were simulated with different assumptions about the integrity of the components of the barrier system. For the design case, the multi-barrier system was shown to be effective in diverting infiltration water around the vaults containing radioactive waste. Nevertheless, the volatile radionuclide 14C migrates outside the containment system and through the unsaturated zone, driven by gas diffusion. 3 H is largely contained within the vaults where it decays, with small amounts being flushed out in the liquid state. Various scenarios were examined in which the integrity of the cover barrier system or that of the concrete were compromised. In the absence of any engineered barriers, 3 H is washed out to the water table within the first 20 years. The release of 14C by gas diffusion is suppressed if percolation fluxes through the facility are high after a cover failure. However, the high fluxes lead to advective transport of 14C dissolved in the liquid state. The concrete container is an effective barrier, with approximately the same effectiveness as the cover.

본 연구는 경주 중·저준위처분장 2단계 표층처분시설의 폐쇄 후 안전성에 대한 불확실성을 예측·평가하기 위하여 수행되 었다. 다중덮개와 처분고의 건전/열화를 고려한 총4가지의 시나리오를 도출하여 강우침투 시 예상되는 처분시설 내부의 유 체 이동을 모사하였다. 강우 조건은 총 30년(1985~2014) 간의 월평균 데이터를 적용하였으며, 시뮬레이션 기간은 제도적 관 리기간인 300년으로 설정하였다. 처분덮개와 처분고 콘크리트 모두 건전성을 유지하는 조건의 기본 시나리오 평가 결과, 처 분시설 내부의 처분고를 완전히 포화시키지 못하는 것을 확인할 수 있었다. 다중 덮개층을 구성하는 8개 층의 각 매질의 모 세관 압력과 투과도 차이로 인하여 다중 덮개층이 효과적으로 차수·배수 역할을 하는 것으로 나타났다.

본 연구에서는 중·저준위방사성폐기물 처분시설(이하 처분시설)에서 발생하는 기체의 이동현상을 예측하기 위한 2차원 수 치 모델링을 수행하였다. 또한, 기체 이동 모델링에서 주요 입력변수로 적용되는 사일로 콘크리트의 기체침투압(gas entry pressure)와 기체 투과도(gas permeability)를 실측하여, 모델링 입력변수로 적용하였다. 사일로 콘크리트의 기체침투압(gas entry pressure)와 기체 투과도(gas permeability)는 각각 0.97±0.15 bar 및 2.44×10-17 m2로 측정되었다. 기체 이동 모델링 결과, 사일로 내부에서 발생하는 수소 기체는 기상으로 이동하지 않고 지하수에 용해되어 지하수와 함께 생태계로 이동하는 것을 알 수 있다. 또한, 폐쇄 후 약 1,000 년 후 부터 사일로 상부부터 수소기체 밀도가 증가하기 시작하는 것으로 예측되었 다. 따라서, 사일로 내부에서 발생된 기체는 기상으로 사일로 내부에 축적되지 않으며, 이로 인해 사일로 콘크리트의 내구성 에 영향을 미치지 않을 것으로 판단된다.