본 연구에서는 비용매 유도 상분리법을 이용하여 폴리에테르이미드 계열의 중공사형 분리막을 제조하였다. 제조 된 중공사막의 모폴로지 조절을 위해 첨가제로는 THF, Ethanol, LiNO3를 사용하였다. 또한 높은 수소분리막의 개발을 위해 모폴로지와 기체투과성능을 특성평가를 통해 방사조건을 최적화하였다. 그 결과 THF의 함량이 증가할수록 수소/이산화탄소 선택도가 증가하였다. 하지만 trade-off 관계로 인하여 투과율은 감소하였다. Ethanol을 첨가하였을 때는 finger-like 구조를 나타냈고, LINO3를 첨가하였을 때 Sponge 구조를 보였다. 특히, PDMS 코팅층을 최적화한 중공사막의 경우, 투과율은 40 GPU, 수소/이산화탄소 선택도는 5.6을 나타냈다.

본 연구에서는 polyketone (PK)을 이용하여 전기방사 조건에 따른 섬유 형상의 특성 변화와 유수분리 가능성을 확인해 보았다. 고습과 저습 조건에서는 마이크론 직경의 섬유가 형성되었으며, 특히 고습에서는 섬유의 표면이 거칠게 변한 것이 확인되었다. 섬유 직경을 micro에서 nano로 변경하기 위하여 방사용액에 염을 추가하였으며, 그 결과 섬유 직경이 약 90% 감소하는 것을 확인할 수 있었다. 제조된 rPK-LNC와 PK-H로 유수분리 특성을 확인하기 위해 oil/water 에멀션으로 중 력 조건에서 유수분리를 진행하였으며 total organic carbon (TOC)와 탁도를 측정하여 특성을 분석하였다. 제거율 확인결과 탁도가 TOC와 동일한 경향성을 나타내는 것이 확인되었다. 따라서 본 연구에서는 고분자의 방사조건과 염의 유무에 따른 분리막의 섬유 형상과 물리적 특성변화와 이를 이용한 유수분리 특성에 대해 연구하였다.

PURPOSES : The percentage of vehicle overturning accidents is 16.3% of vehicle alone fatal accidents, with a fatality rate of 9.0%, accounting for a high proportion, and heavy vehicles with a high center of gravity are vulnerable to overturning accidents. In the standard guidelines of Super-Bus Rapid Transit(S-BRT), it is recommended to install physical facilities that separate buses from other traffic on dedicated bus ways, and lane separation facilities are being developed. To develop low-profile lane separation facilities that do not interfere with sight obstruction for pedestrians and drivers, it is necessary to review the height of lane separation facilities to prevent overturning crashes of heavy vehicles. METHODS : Heavy vehicle impact conditions of 8ton-55km/h-15°, 8ton-55km/h-20°, 8ton-65km/h-15°, and 8ton-65km/h-20°were applied to compare the vehicle behavior by the height of lane separation facilities using LS-DYNA, a three-dimensional nonlinear impact analysis program based on speed and angle changes. In addition, the behavior of the vehicle after the collision was analyzed to examine the impact conditions in which an overturning crash occurs when a heavy vehicle collides with a low-profile lane separation facility and the appropriate height of the facility to prevent overturning. RESULTS : In general, under the 8ton-65km/h-15°condition, which is a heavy vehicle impact condition used in the performance standard of the barrier, the vehicle’s behavior after the collision was stable as the height of the lane separation facility increased. CONCLUSIONS : Therefore, when the impact conditions were 8ton-65km/h-15°or less, it was determined that the appropriate height to prevent the condition of the lane separation facility was 400mm or more.

PURPOSES : According to the guidelines of Super Bus Rapid Transit(BRT), dedicated bus roads and dedicated bus lanes shall be used, and physical lane separation facilities should be installed for lane separation. Therefore, physical barriers (lane separation facilities) are being developed for exclusive bus operations. Low-profile lane separation facilities should be developed that do not interfere with the views of pedestrians and drivers. The appropriate heights of the barrier to prevent overriding in the event of passenger car crashes were reviewed. METHODS : By applying the performance standards of the safety barrier, passenger protection performance according to the change in the height of the lane separation facilities and the vehicle behavior after the crash were analyzed using computer crash simulations. Crash criteria of 1.3 ton-60 km/h-20°and 1.3 ton-80 km/h-20°were used as vehicle impact conditions. The simulation was performed by increasing the height of the lane separation facilities from 200 mm to 500 mm. To prevent the deformation of the lane separation facilities owing to a vehicle crash, the boundary conditions of the node under the lane separation facilities were fixed and modeled. RESULTS : The collision simulation results showed that, for a collision speed of 60 km/h, no override occurred for the height of the lane separation facility of 250 mm or more, and for a collision speed of 80 km/h, no override occurred for the height of the lane separation facility of 300 mm or more. CONCLUSIONS : Therefore, the appropriate height of the lane separation facility for the collision of a passenger car with a collision speed of 80 km/h or less was determined to be 300 mm or more.