BaMoO4:Tb3+ phosphor powders were synthesized with different concentrations of Tb3+ ions using the solid-state reaction method. XRD patterns showed that all the phosphors, irrespective of the concentration of Tb3+ ions, had tetragonal systems with two main (112) and (004) diffraction peaks. The excitation spectra of the Tb3+-doped BaMoO4 phosphors consisted of an intense broad band centered at 290 nm in the range of 230-330 nm and two weak bands. The former broad band corresponded to the 4f8 →4f75d1 transition of Tb3+ ions; the latter two weak bands were ascribed to the 7F2→ 5D3 (471 nm) and 7F6→ 5D4 (492 nm) transitions of Tb3+. The main emission band, when excited at 290 nm, showed a strong green band at 550 nm arising from the 5D4→ 7F5 transition of Tb3+ ions. As the concentration of Tb3+ increased from 1 to 10 mol%, the intensities of all the emission lines gradually increased, approached maxima at 10 mol% of Tb3+ ions, and then showed a decreasing tendency with further increase in the Tb3+ ions due to the concentration quenching effect. The critical distance between neighboring Tb3+ ions for concentration quenching was calculated and found to be 12.3 Å, which indicates that dipoledipole interaction was the main mechanism for the concentration quenching of the 5D4→ 7F5 transition of Tb3+ in the BaMoO4:Tb3+ phosphors.
Detailed low spectral resolution observations of the spectrum have been made for three early spectral type standard stars, HR718, HR1544, HR3454, respectively, for the wavelength region 4,300 A to 7,500 A, using the Bohyunsan Optical Astronomy Observatory (BOAO) Middle- Dispersion Spectrograph. These standard stars were chosen from well-known bright northern standard stars. All of the observed long slit spectral data has been reduced and analyzed using the IRAF reduction procedure. The derived extinction coefficients are compared with the other observatory result. The derived value can be used in the determination of flux calibration of BOAO spectroscopic observation. However, until the high quality data are secured from a new series of observation in the blue region and are re-analyzed together, the extinction coefficients below the 4,000 A wavelength remains unknown.