Recently, retrofit by using fiber reinforced polymer (FRP) has been widely applied to building structure. However, it loose the retrofit contribution under high temperature due to fire because of its low glass transition temperature. In this manner, this paper presents a study on the development of fire resistant capacity in FRP retrofit system. Thermal transition of various fire resistant materials were verified by performing high temperature loading test. As a result, it was found that calcium silicate and alumino silicate had high resistance on the heat transition.