The dyeing process is a very important unit operation in the leather and textile industries; it produces significant amounts of waste effluent containing dyes and poses a substantial threat to the environment. Therefore, degradation of the industrial dye-waste liquid is necessary before its release into the environment. The current is focusing on the reduction of pollutant loads in industrial wastewater through remediating azo and thiazine dyes (synthetic solutions of textile dye consortium). The current research work is focused on the degradation of dye consortium through photo-electro-Fenton (PEF) processes via using dimensionally stable anode (Ti) and graphite cathode. The ideal conditions, which included a pH of 3, 0.1 (g/L) of textile dye consortium, 0.03 (g/L) of iron, 0.2 (g/L) of H2O2, and a 0.3 mAcm-2 of current density, were achieved to the removal of dye consortium over 40 min. The highest dye removal rate was discovered to be 96%. The transition of azo linkages into N2 or NH3 was confirmed by Fourier transforms infra-red spectroscopic analysis. PEF process reduced the 92% of chemical oxygen demand (COD) of textile dye consortium solution, and it meets the kinetics study of the pseudo-first-order. The degradation of dye through the PEF process was evaluated by using the cyclic voltammetric method. The toxicity tests showed that with the treated dye solution, seedlings grew well.

The electro-Fenton (EF) process was first proposed in 1996 and, since then, considerable development has been achieved for its application in wastewater treatment, especially at lab and pilot scale. After more than 25 years, the high efficiency, versatility and environmental compatibility of EF process has been demonstrated. In this review, bibliometrics has been adopted as a tool that allows quantifying the development of EF as well as introducing some useful correlations. As a result, information is summarized in a more visual manner that can be easily analyzed and interpreted as compared to conventional reviewing. During the recent decades under review, 83 countries have contributed to the dramatic growth of EF publications, with China, Spain and France leading the publication output. The top 12 most cited articles, along with the top 32 most productive authors in the EF field, have been screened. Four stages have been identified as main descriptors of the development of EF throughout these years, being each stage characterized by relevant breakthroughs. To conclude, a general cognitive model for the EF process is proposed, including atomic, microscopic and macroscopic views, and future perspectives are discussed.

To increase electrolysis performance, the applicability of seawater to the iron-fed electro-Fenton process was considered. Three kinds of graphite electrodes (activated carbon fiber-ACF, carbon felt, graphite) and dimensionally stable anode (DSA) electrode were used to select a cathode having excellent hydrogen peroxide generation and organic decomposition ability. The concentration of hydrogen peroxide produced by ACF was 11.2 mg/L and those of DSA, graphite, and carbon felt cathodes were 12.9 ~ 13.9 mg/L. In consideration of durability, the DSA electrode was selected as the cathode. The optimum current density was found to be 0.11 A/cm2, the optimal Fe2+ dose was 10 mg/L, and the optimal ratio of Fe2+ dose and hydrogen peroxide was determined to be 1:1. The optimum air supply for hydrogen peroxide production and Rhodamine B (RhB) degradation was determined to be 1 L/min. The electro-Fenton process of adding iron salt to the electrolysis reaction may be shown to be more advantageous for RhB degradation than when using iron electrode to produce hydrogen peroxide and iron ion, or electro-Fenton reaction with DSA electrode after generating iron ions using an iron electrode.