Expansive clays (for examples, bentonites) are favored as buffer and backfill materials because of their low hydraulic conductivity, high swelling potential, and good mechanical properties, and are installed in highly compacted blocks in repositories. Compacted expansive clays have a dual-structure system: macrostructural system which is a complex of clay aggregates with the inter-aggregate pores (macropores) which can be filled by either liquids or gases; microstructural system with the intraaggregate pores between or within clay particles (micropores) which is usually considered to be saturated by liquid. Understanding the dual-strucure system of expansive clays is essential for characterizing and modeling multiphysics (stress-strain, swelling pressure, etc.) in buffers and backfills. Existing multiphysics studies of expansive clays, as in non-expansive soils, were mostly conducted with a single structure approach based on the behavior of macropores, and there have been limitations in the comprehensive interpretation and modeling of experimental results. However, with the recent development of measurement techniques, a lot of available information on the pore structure of compacted expansive clays has been reported, and with the results, a dual-structure approach considering both microstructural and macrostructural systems has been increasingly applied to improve the modeling of multiphysics of expansive clays. This study reviewed the dual-structure system of compacted expansive clays, analyzed previous studies on its evolution according to hydromechanical loading (loading-unloading and wetting-drying paths), and based on these, intended to provide technical knowledge and information needed for multiphysics research of expansive clays-based buffer and backfill for the KRS repository.