본 연구에서는 합성가스 CO를 생산하기 위해 저급 석탄-CO2 촉매 가스화 실험을 수행하였 다. 제조된 CO가스 특성은 키데코 탄과 신화 탄에 KOH, K2CO3, Na2CO3 촉매들의 화학적 활성화 방 법을 이용하여 조사되었다. CO 제조공정은 석탄과 화학약품 활성화 비율, 가스 유량, CO2 전환 반응온 도와 같은 실험 변수 분석을 통해 최적화되었다. 제조된 합성 가스는 가스 크로마토그래피(GC)에 의해 분석 되었다. 실험조건 T = 950 °C, CO2 유량 100 cc/min에서, 20 wt% Na2CO3가 혼합된 키데코 탄 에 대해 98.6%, 20 wt% KOH가 혼합된 신화탄에 대한 98.9% CO2 전환율을 얻었다. 또한, 저급 석탄-촉매 가스화 반응은 동일한 공급 비와 반응 조건에서 97.8%, 98.8%의 CO 선택도를 얻었다.

It has been studied that combustion and the production of air pollution of anthracite - bituminous coal blend in a fluidized bed coal combustor. The objects of this study were to investigate mixing characteristics of the particles as well as the combustibility of the low grade domestic anthracite coal and imported high calorific bituminous coal in the fluidized bed coal combustor. They were used as coal samples ; the domestic low grade anthracite coal with heating value of 2,010㎉/㎏ and the imported high grade bituminous coal with heating value of 6,520㎉/㎏. Also, the effects of air flow rate and anthracite fraction on the reaching time of steady state condition have been studied. The experimental results are presented as follows. The time of reaching to steady state was affected by the temperature variation. The steady state time was about 120 minute at 300scfh which was the fastest. It has been found that O_2 and CO_2 concentration were reached steady state at about 100 minute. It has been found that O_2 concentration decreased and CO_2 concentration increased as the height of fluidized bed increased. It was found that splash zone was mainly located from 25㎝ to 35㎝ above distributor. Also, as anthracite fraction increased, the mass of elutriation particles increased, and CO_2 concentration decreased. As air flow rate increased, O_2 concentration decreased and CO_2 concentration increased. Regardless of anthracite fraction and flow rate, the uncombustible weight percentage according to average diameter of elutriation particles were approximately high in the case of fine particles. As anthracite fraction and air flow rate increased, elutriation ratio increased. As anthracite fraction was increased, exit combustible content over feeding combustible content was increased. Regardless of anthracite fraction, size distribution of bed material from discharge was almost constant. Over bed temperature 850℃ and excess air 20%, the difference of combution efficiencies were little. It is estimate that the combustion condition in anthracite-bituminous coal blend combustion is suitable at the velocity 0.3m/s, bed temperature 850℃, the excess air 20%.