The MFFn(Mass First Flush) was analyzed for various rainy events(monitoring data from 2008 to 2009) in Transportation area(Highway, National road, Trunk road). Estimated MFFn using SWMM was evaluated by comparison with observed MFFn. MFFn was estimated by varying n-value from 10% to 90% on the rainy events. The n-value increases, MFFn is closed to '1'. As time passed, the rainfall runoff was getting similar to ratio of pollutants accumulation. The result of a measure of the strength of the linear relationship between observed data and expected data under model was good (R2=0.89). Pollutants runoff loads by volume showed Highway 26.6%, National road 44.8%, Trunk road 35.0% at the MFF20(20% by total runoff). A case of MFF30, pollutants runoff loads by volume showed Highway 40.2%, National road 54.3%, Trunk road 46.8%. According to the results, Initial precipitation basis were Highway MFF30, National road MFF20, Trunk road MFF30 when the Non-Point source control facilities set up.