Air conditioning facilities in nuclear power plants use pre-filters, HEPA filters, activated carbon filters, and bag filters to remove radionuclides and other harmful substances in the atmosphere. Spent filters generate more than 100 drums per year per a nuclear power plant and are stored in temporary radioactive waste storage. Plasma torch melting technology is a method that can dramatically reduce volume by burning and melting combustible, non-flammable, and mixed wastes using plasma jet heat sources of 1,600°C or higher and arc Joule heat using electric energy, which is clean energy. KHNP CRI & KPS are developing and improving waste treatment technology using MW-class plasma torch melting facilities to stably treat and reduce the volume of radioactive waste. This study aims to develop an operation process to reduce the volume of bag filter waste generated from the air conditioning system of nuclear power plants using plasma torch melting technology, and to stably treat and dispose of it. It is expected to secure stability and reduce treatment costs of regularly generated filter waste treatment, and contribute to the export of radioactive waste treatment technology by upgrading plasma torch melting technology in the future.
After the Fukushima accident, significant amount of radioactively contaminated waste has been generated with 50~250 m3/day and stored in tanks of the Fukushima Daiichi nuclear power plant site. The contaminated water is treated by various treatment facility such as KURION, SARRY, Reverse Osmosis, and ALPS to remove 62 radioactive nuclides except H-3. For the contaminated water treatment process, massive secondary wastes such as sludge, spent adsorbent, and so on as by-product are being generated by the facilities. In Japan, to treat the secondary wastes, melting technologies such as GeoMelt, In-can vitrification and Cold Crucible Induction Melting vitrification are considered as a candidate technologies. In this study, the technologies were reviewed, and the advantage and disadvantage of each technology were evaluated as the candidate technologies for treatment of the secondary wastes.
Plasma melting technology is a high-temperature flame of about 1,600°C or higher generated using electrical arc phenomena such as lightning, and radioactive waste generated during the operation and dismantling of nuclear power plants is not classified according to physical characteristics. It is a technology that can meet waste disposal requirements through treatment and reduction. Plasma torch melting technology was used for volume reduction and stable treatment of HVAC filters generated from nuclear power plants HVAC (Heating Ventilation and Air Conditioning). filter was treated by placing 1 to 3 EA in a drum and injecting it into a plasma melting furnace at 1,500°C, and the facility was operated without abnormal stop. A total of 132.5 kg of filter was treated, and the high-temperature melt was normally discharged four times. It was confirmed that the plasma torch melting facility operates stably at 500 LPM of nitrogen and 370-450 A of current during filter treatment. Through this study, the possibility of plasma treatment of filters generated at nuclear power plants has been confirmed, and it is expected that stable disposal will be possible in the future.
The liquid radioactive waste system of nuclear power plants treats radioactive contaminated wastes generated during the Anticipated Operational Occurrence (AOO) and normal operation using filters, ion exchange resins, centrifuges, etc. When the contaminated waste liquid is transferred to an ion exchanger filled with cation exchange resin and anion exchange resin, nuclides such as Co and Cs are removed and purified. The lifespan and replacement time of the ion exchange resin are determined by performing a performance test on the sample collected from the rear end of the ion exchanger, and waste ion exchange resin is periodically generated in nuclear power plants. In the general industry, most waste resins at the end of their lifespan are incinerated in accordance with related laws, but waste resins generated from nuclear power plants are disposed of by clearance or stored in a HIC (High Integrity Container). Plasma torch melting technology can reduce the volume of waste by using high-temperature heat (about 1,600 degrees) generated from the torch due to an electric arc phenomenon such as lightning, and secure stability suitable for disposal. Plasma torch melting technology will be used to check thermal decomposition, melting, exhaust gas characteristics, and volume reduction at high temperatures, and to ensure disposal safety. Through this research, it is expected that the stable treatment and disposal of waste resins generated from nuclear power plants will be possible.
Currently, KHNP has 24 operating nuclear power plant units with a toal combined capacity of about 23 GWe and two units are under construction. However, permanent stop of Kori unit 1 nuclear power plant was decided in 2017. Accordingly, interest in how to dispose of waste stored inside a permanently stopped nuclear power plant and waste generated as decommissioning process is increasing. KHNP CRI is conducting research on the advancement of plasma torch melting facilities for waste treatment generated during the plant decommissioning and operation period. Plasma torch melting facility is composed of various equipment such as a melting furnace (Melting chamber, Pyrolsis chamber), a torch, an exhaust system facility, a waste supply device, and other equipment. In demonstration test, concrete waste was put in a 200 L drum to check whether it can be pyrolyzed using a plasma torch melting facility. Reproducibility for waste treatment in the form of a 200 L drum and discharge of molten slag could be confirmed, the amount of concrete waste in 200 L Drum that could be treated according to power of plasma torch was confirmed. This demonstration test confirmed the field applicability and stability of plasma torch melting facility, and improved expectations for long-term operation.
In nuclear power plants, insulation is used to protect equipment and block heat. Insulation materials include asbestos, glass fiber, calcium silicate, etc. Various types and materials are used. This study aims to ensure volume reduction and disposal safety by applying plasma torch melting technology to insulation generated at operating and dismantling nuclear power plants. After the evaluation of characteristics by securing thermal insulation materials or similar materials in use at the operational and dismantling nuclear power plant. It is planned to perform pyrolysis and melting tests using the MW plasma torch melting facility owned by KHNP CRI Before the plasma test, check the thermal decomposition and melting characteristics (fluidity, etc.) of the insulation in a 1,600°C high-temperature furnace. The insulation is stored in a 200 L drum and injected into a plasma facility, and the drum and the insulation are to be pyrolyzed and melted by the high temperature inside the plasma torch melting furnace. Through this test, thermal decomposition and melting of the insulation, solidification/ stabilization method, maximum throughput, and exhaust characteristics are confirmed at a high temperature (1,600°C) of the plasma torch. Through this study, it is expected that the stable treatment and disposal of insulation generated from operating and dismantling nuclear power plants will be possible.
원자력시설의 해체 시 발생되는 금속폐기물의 양은 전 세계적으로 향후 50년 동안 스테인레스강 약 95 만톤, 탄소강 870 만 톤, 구리 220 만 톤으로 총 1,200 만 톤 정도 발생할 것으로 예측되고 있다. 해체 시 발생하는 금속 조각은 대부분 방사능에 아주 미미하게 오염되어 있기 때문에 이중에서 대부분은 무구속 방출이나 약간의 제염 처리 후 일정한 공정을 거쳐 핵 시설내의 폐기물 저장 용기나 처분 상자, 폐기물 드럼, ISO 컨테이너 등으로 재활용되고 있거나, 앞으로 재활용할 수 있다고 보고되고 있다. 국내 원자력시설 해체 시 다량으로 발생될 것으로 예상되는 금속 조각을 수용하기에는 폐기물 처리장이 매우 부족할 뿐만 아니라, 지속적으로 처분 단가의 증가가 예상되므로 이러한 문제를 해결하기 위해서 방사성 금속폐기물의 효과적인 감용 및 재활용 기술이 요구되고 있다. 금속 폐기물의 감용 및 재활용 기술 중 현재까지 가장 적절한 기술로서 용융 기술이 있다. 유럽을 주축으로 미국과 일본에서 활발히 연구되어져 온 용융 기술은 다른 처분 방법에 비해 부피 감용비가 가장 높아 최종처분시설 공간을 절약할 수 있으며 탄소강, 스테인레스강 및 인코넬 등 많은 양의 금속을 회수하는 것이 가능하다. 또한, 이 기술은 휘발성 핵종(Cs 등)이나 금속과 반응성이 적은 핵종(U, Pu 등)을 슬래그 속에 포집하여 제염하거나, 방사성 핵종들이 주괴에 균일하게 분포하고 금속의 결정 격자속에 고정화시킬 수 있기 때문에 보다 안정화시킬 수 있다는 장점들을 가지고 있다.