This study evaluated the field applicability of a real-time odor monitoring system combined with ozone water spraying technology to effectively control odors generated in livestock manure recycling facilities. Research was conducted at a Natural Circulation Agriculture Center located in N City, where concentrations of ammonia (NH3), hydrogen sulfide (H2S), and volatile organic compounds (VOCs) were measured in real time. Based on real-time data, ozone water was sprayed to assess the odor reduction rate, and the impact on surrounding areas was predicted through odor dispersion modeling. The results showed that the ammonia concentration measured at the upper section of the liquid aeration tank before ozone water spraying was 8.02 ppm, exceeding the emission limit of 1 ppm. VOCs were also found to have significantly contributed to odor generation. However, after spraying ozone water at a rate of 7 L/min and maintaining a concentration of 2.5 mg/L, ammonia was reduced by approximately 50%, and VOCs were reduced by about 98%, demonstrating a strong odor-reducing effect. Odor dispersion modeling using the CALPUFF modeling system simulated the range of odor dispersion before and after ozone water spraying. The results indicated that after ozone water spraying, the ammonia concentration at the facility boundary met the emission limit, effectively suppressing odor dispersion. In particular, the ozone water spraying system linked with the real-time sensor enabled automated odor control based on real-time data, demonstrating its potential for resolving odor complaints and ensuring compliance with environmental regulations.
In this study, the odor generated in a livestock farm with 500 heads of finisher breed in 661 m² was monitored during 6 months using a gas sensor, a wired / wireless communication system and database server. Odor unit, ammonia, hydrogen sulfide, and total volatile organic compounds (TVOC) were monitored using the gas sensor. To show the tendency of odorous substances generation, the odor concentration was shown in the graph on a monthly and daily basis. Among the analysis items, the maximum generation of odor was found to be closely related to the generation of hydrogen sulfide. Through observing the daily and monthly trends of odor substances, it was found that each substance was a useful indicator for monitoring odor, because ammonia, hydrogen sulfide, odor and TVOC were increased and decreased in a similar pattern. The odors were highest in the hours of the early morning (00:00-05:00), the evening (18:00-23:00), and the morning (06:00-11:00) in a day. After the use of the microbial agent was discontinued in autumn (October), anaerobic digestion of the manure in a pit proceeded and the amount of hydrogen sulfide increased. Therefore, despite a slight decrease in ammonia production, the odor unit level did not decrease after October but rather was somewhat increased. In the future, the use of the odor monitoring system is expected to improve the efficiency of odor sources management.