The thermal treatment of radioactive waste attracts great attention. The thermal treatment offers lots of advantages, such as significant volume reduction, hazard reduction, increase of disposal safety, etc. There are various thermal technologies to waste. The developed technologies are calcination, incineration, melting, molten salt oxidation, plasma, pyrolysis, synroc, vitrification, etc. The off-gas treatment system is widely applied in the technologies to increase the safety and operation efficiency. The thermal treatment generates various by-product and pollutants during the process. The dust or fly ash are generated as a particulate from almost every radioactive waste. The treatment of PVC related components generates hydrogen chloride, which usually brings corrosion of facility. The treatment of rubber and spent resin generates sulfur oxide, SOx. The treatment of nitrile rubber generates nitrogen oxide, NOx. The incomplete combustion of radioactive waste usually generates carbon oxide, COx. The process temperature also affects the generation of off gas, such as NOx and/or COx. Various off gas treatment components are organized for the proper treatment of the previously mentioned materials. In this study systematical review on off gas treatment will be reported. Also, worldwide experiences and developed facility will be reported.

The purpose of this study was to develop a recycling system for ozone off-gas. Although the ozone transmission rate of the injector method differs slightly depending on the ozone injection rate, it reaches approximately 99%, which is very high. During the increase in water inflow to the ozone recycling system from 2 L/min to 10 L/min, the average ozone recycling rate was 99.4% at a 1 ppm ozone injection rate, 98.6% at a 2 ppm ozone injection rate, 98.1% at a 3 ppm ozone injection rate. Ozone treatment facility operating costs can be divided into the costs of pure oxygen production, ozone production, and maintenance. The annual operating costs of ozone treatment facilities in Korea are estimated to be approximately 38.9 billion won. The annual savings are estimated to be approximately 5.8 billion won when the ozone transfer rate of the diffuser method, which is mostly employed in domestic water treatment plants, is 85% and 15% of the ozone is recycled.