Swelling of the heat-treated netting for gillnet was estimated through the netting height in square acrylic tank. Experimental Nylon netting and PBSAT netting were heat-treated by using the high-degree vacuum method in hot water after net making. Heat-treatment temperatures were conducted with Nylon netting 105°C and PBSAT netting 62°C, 65°C, 66°C, 67°C. The swelling measurement method of a netting using the square tank was capable of the reduction measurement errors comparing with measurement methods of a mesh inner angle and the shortening rate of a mesh size. In addition, this method was available to comparison evaluation for each netting more easily. Wet type heat-treatment apparatus with high-degree vacuum was shown higher 7∼8°C inner side temperature than a setting temperature. The tensile strength and elongation of Nylon netting and PBSAT netting were shown higher wet condition than dry condition. The tensile strengths of PBSAT monofilaments in dry and wet condition were sharply decreased at heat-treatment temp. 75°C than heat-treatment temp. 74°C
The monofilament with 0.304mm of diameter was produced using a polybutylene succinate (PBS) resin, and a gill net was made by it. We investigated the impact of heat setting temperature on the mechanical properties, knot state and height of gill net. Heat treatment was carried out using the high pressure steam machine for 20 minutes at temperature of 55℃, 60℃, 70℃ and 75℃. Before heat treatment, the strength and elongation of PBS monofilament were estimated to be 48.1kg/mm2, 23.8% at unknot, 37.6kg/mm2, 18.8% at single knot, 26.6kg/mm2, 22.9% at double knot in dry condition, respectively. The strength and elongation of PBS monofilament with double knot were decreased as heat setting temperature increased, and the decreasing rate of strength was showed to be higher than that of elongation. It was not found any differences in strength and elongation of PBS monofilament yarn with double knot at the 65℃ and 70℃ of heat setting temperature by 5% significance of T-test, but there was a significant difference at the 70℃ and 75℃ of heat setting temperature. The net's height and length from leg to leg appeared no differences at the 70℃ and 75℃ of heat setting temperature. In results, it was investigated that the PBS monofilament gill net with the maximized physical properties could be manufactured at 70℃ of heat setting temperature using a high pressure steam machine for 20 minutes.
Biodegradable polybutylene succinate(PBS) is an environment friendly plastics for fisheries, because it can mitigate the ghost fishing problem caused by gill-net and trap fisheries. To evaluate photodegradability of PBS monofilament in comparison with polyamide(PA) and polyethylene(PE) monofilament, these 3 types of monofilaments were spun and exposed to ultraviolet light(UV) of weather-ometer for 900 hours, and then their modification, crystal structure, strength, and extensibility were analysed. PBS monofilament did not show any crack and maintained its crystal structure after 900 hour exposure to UV whereas PE monofilament began showing cracks and structure modification after 600 hour exposure. Under UV exposure, the strength and extensibility decreased more rapidly in PBS than in PA and PE. We estimate that gill nets made of PBS monofilament can endure for about 1 year. The breaking strength and elongation decreased linearly with the exposure time for the 3 types of monofilaments. The derived regression equations of the residual tenacity(RT, kg/mm2) and the residual extensibility(RE, %) with the exposure time in year(Y) for each monofilament were; PBS : RT=48.598 - 8.6437Y(R2=0.93), RE=28.165 - 7.3233Y(R2=0.98), P A : RT=59.771 - 8.6437Y(R2=0.98), RE=32.198 - 5.2772Y(R2=0.92), P E : RT=60.898 - 5.6528Y(R2=0.98), RE=11.887 - 0.7188Y(R2=0.98).