Pressurized Heavy Water Reactors (PHWR) have stored ion exchange resins, which are used in deuteration, dehydrogenation systems, liquid waste treatment systems, and heavy water cleaning systems, in spent resin storage tanks. The C-14 radioactivity concentration of PHWR spent resin currently stored at the Wolseong Nuclear Power Plant is 4.6×10E+6 Bq/g, which exceeds the limited concentration of low-level radioactive waste. In addition, when all is disposed of, the total radioactivity of C-14, 1.48×10E+15 Bq, exceeds the disposal limit of the first-stage disposal facility, 3.04×10E+14. Therefore, it is currently impossible to dispose of them in Gyeongju intermediate- and low-level disposal facilities. As to dispose of spent resins produced in PHWR, C-14 must be removed from spent resins. This C- 14 removal technology from the spent resin can increase the utilization of Gyeongju intermediate- and low-level disposal facilities, and since C-14 separated from the spent resin can be used as an expensive resource, it is necessary to maximize its economic value by recycling it. The development of C-14 removal technology from the spent resin was carried out under the supervision of Korea Hydro & Nuclear Power in 2003, but there was a limit to the C-14 removal and adsorption technology and process. After that, Sunkwang T&S, Korea Atomic Energy Research Institute, and Ulsan Institute of Science and Technology developed spent resin treatment technology with C-14-containing heavy water for the first and second phases from 2015 to 2019 and from 2019 to the present, respectively. The first study had a limitation of a pilot device with a treatment capacity of 10L per day, and the second study was insufficient in implementing the technology to separate spent resin from the mixture, and it was difficult to install on-site due to the enlarged equipment scale. The technology to be proposed in this paper overcomes the limitations of spent resin mixture separation and equipment size, which are the disadvantages of the existing technology. In addition, since 14CO2 with high concentration is stored in liquid form in the storage tank, only the necessary amount of C-14 radioactive isotope can be extracted from the storage tank and be used in necessary industrial fields such as labeling compound production. Therefore, when the facility proposed in this paper is applied for treating mixtures in spent resin tanks of PHWR, it is expected to secure field applicability and safety, and to reflect the various needs of consumers of labeled compound operators utilizing C-14.

According to the ‘Basic Plan for High-Level Radioactive Waste Management (draft)’, the total amount of CANDU spent nuclear fuel is expected to be approximately 660,000 bundles. To safely and efficiently transport this amount to interim storage facilities, it is essential to develop a large-capacity transport cask. Therefore, we have been developing a large-capacity PHWR spent nuclear fuel transport cask, called the KTC-360 transport cask. According to the transport-cask related regulations, the KTC-360 transport cask was classified as a Type B package, and such packages must be able to withstand a temperature of 800°C for a period of 30 min. It is desirable to conduct a test using a fullscale model of a shipping package when performing tests to evaluate its integrity. However, it is costly to perform a test using a full-scale model. Therefore, to evaluate the thermal integrity of the KTC-360 transport cask, the fire test was conducted using a slice model. For comparison purposes, the fire test was also carried out using a 1/4 scale model. In the fire test using a slice model and in the fire test using a 1/4 scale model, the maximum temperature of the cask body was lower than the permitted maximum temperature limit. Therefore, the thermal integrity of the KTC-360 transport cask could be considered to be maintained. The temperature results from the fire test using a slice model were higher than those of the fire test using a 1/4 scale model. Therefore, the effect of flame on a transport cask without combustible materials, such as the KTC-360 transport cask, seems to be affected by the reduction in the time rather than the size reduction.

The safety of a KTC-360 transport cask, a large-capacity pressurized heavy-water reactor transport cask that transports CANDU spent nuclear fuel discharged from the reactor after burning in a pressurized heavy-water reactor, must be demonstrated under the normal transport and accident conditions specified under transport cask regulations. To confirm the thermal integrity of this cask under normal transport and accident conditions, high-temperature and fire tests were performed using a one-third slice model of an actual KTC-360 cask. The results revealed that the surface temperature of the cask was 62°C, indicating that such casks must be transported separately. The highest temperature of the CANDU spent nuclear fuel was predicted to be lower than the melting temperature of Zircaloy-4, which was the sheath material used. Therefore, if normal operating conditions are applied, the thermal integrity of a KTC-360 cask can be maintained under normal transport conditions. The fire test revealed that the maximum temperatures of the structural materials, stainless steel, and carbon steel were 446°C lower than the permitted maximum temperatures, proving the thermal integrity of the cask under fire accident conditions.