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        검색결과 7

        1.
        2024.10 KCI 등재 구독 인증기관 무료, 개인회원 유료
        본 연구는 해조류인 괭생이 모자반을 탄화하여 만든 바이오차의 중금속 흡착 및 제거 효과를 확인하고 중금속 흡착제로 이용 가능성을 확인하고자 연구가 수행되었다. 모자반 바이오차(SBC)는 500℃조건에서 2시간 열분해를 통해 생산하였다. 중금속 흡착실험은 Pb, Cd, Cu 및 Zn의 각 농도별 흡착량을 확인하였으며, Freundlich 및 Langmuir 등온흡착모델을 통해 중금속 흡착 효율성을 확인하였다. 모자반 바이오차의 중금속 제거효율은 Pb, Cd, Cu 및 Zn에서 각각 97.3, 85.2, 76.4 및 42.0%로 Pb>Cd>Cu>Zn 순의 제거효율을 보였다. 등온흡착결과로 Freundlich 등온흡착패턴은 L형이었으며, 흡착강도(1/n)는 0.49 ~ 0.80 범위로 조사되었다. Langmuir 등온흡착식에서 최대흡착량은 Pb, Cd, Cu 및 Zn에서 각각 200, 92.6, 47.8 및 70.4 mg g-1이었으며, 흡착강도는 각각 0.4950, 0.1004, 0.0245 및 0.0188로 조사되었다. 본 실험 결과로 볼 때 모자반 바이오차는 중금속 흡착제로써 활용이 가능할 것으로 보여지며, 이를 활용하기 위한 추가 연구가 필요하다고 보여진다.
        4,000원
        6.
        1999.06 KCI 등재 서비스 종료(열람 제한)
        Pb2+ and Cr3+ uptake capacity by Sargassum horneri was 185.5㎎ Pb2+/g biomass and 102.6㎎ Cr3-/g biomass, respectively. An adsorption equilibria were reached within about 0.5 hr for Pb2+ and 1 hr for Cr3+. The adsorption parameters for Pb2+ and Cr3+, were determined according to Langmuir and Freundlich model. With an increase in pH values of 2 to 5, Pb2+ uptake was increased, however Cr3+ uptake was constant. The selectivity of mixture solution showed the uptake order of Pb2+>Cu2+>Cr3+>Cd2+. Pb2+ and Cr3+ adsorbed by S. horneri could be recovered from 0.1M HCl, 0.1M HNO3 and 0.1M EDTA by desorption process, and the efficiency of Pb2+ desorption was above 98%, whereas the efficiency of Cr3+ desorption was below 34%.
        7.
        1998.12 KCI 등재 서비스 종료(열람 제한)
        Heavy metal ions in water were removed using algal biomass as adsorbents. Absorbents were dried for 3 days, ground them by 40∼60 mesh and then were swelled in a buffer solution for 1hr. After being packed in the column, commercially available standard solution of Cd(Ⅱ) and Pb(Ⅱ) ions were diluted to get the suitable concentration and then it was eluted with the rate of 1 ㎖/min. Heavy metals on the adsorbents were recovered with nitric acid. More amounts of Cd(Ⅱ) or Pb(Ⅱ) ions in green algae, Ulva pertusa, than in brown algae, Sargassum hornerl, were adsorbed. Pb(Ⅱ) ion was adsorbed more than Cd(Ⅱ) ion in both algae. The pH effect of adsorbed amounts of Cd(Ⅱ), Pb(Ⅱ) ions on the biomass was shown the following order ; pH 10.5 > 8.5 > 7.0 > 5.5 > 3.5. Recovery ratio of metal ions from algae is shown higher in acidic or neural conditions than It in alkalis ones. Pb(Ⅱ) ion is recovered relatively more than Cd(Ⅱ) ion in our system.