This study evaluated the migrant and residue tests of lead (Pb), cadmium (Cd), nickel (Ni), arsenic (As), and antimony (Sb) in 70 tumbler samples. The migration levels of hazardous metals in all the samples were within the migration limits outlined in the Korean standards and specifications for utensils, containers, and packages. Moreover, in all the tumbler samples, only Ni was detected in 0.5% citric acid solution of a food stimulant. The maximum level of Ni 0.0144 mg/L was 14.4% of the migrant specification (not more than 0.1 mg/L), which was relatively safe. The 0.5% citric acid solution was eluted at 4oC, 70oC, and 100oC for 30 min, and only Ni was detected while testing for migration levels according to the temperature variations; all temperature conditions conformed to the standards. The level of Ni migration increased significantly with increasing migration temperature. Regarding the residue level outside the paint-coated tumbler samples, the Pb level was found to range from N.D. to 20638.1323 mg/kg. The risk of Ni was further estimated to be at a safe level of 0.00 to 0.01% compared to the %TDI as a result.

Effect of ball filling ratio on the behavior of balls motion and their collision characteristic in a tumbler-ball milling of metal powder are investigated by a computer simulation. The discrete element method and the extended Kelvin model composed of nonlinear spring and nonlinear dashpot were employed in the simulation. It can be possible that analysis of the individual balls motion in a three-dimensional actual mill by the two-dimensional model simulation, since the simulated trajectories of ball paths are in relatively good agreement with the actual ones. It knows that the balls motion in the tumbler-ball mill is strongly influenced by the surface conditions of the balls and mill container wall. The energy consumption of the individual balls during impact and the impact frequency of the individual balls increased with an increase in the ball filling ratio and showed maximum values at about 50-60% ball filling ratio, and then decreased.