A huge amount of de-icing agent is sprayed during winter to promote traffic safety in cold regions, and the quantity of de-icing agent sprayed has increased each year. The main ingredients in commonly used de-icing agents are chlorides, such as calcium chloride(CaCl2) and sodium chloride(NaCl). While calcium chloride is mostly used in Korea and sodium chloride is usually used in the U.S. and Japan, all de-icing agents include chloride ions. The chlorides included in sprayed calcium chloride-based de-icing agents have severe adverse effects, including the corrosion of reinforcing steels through salt damage by infiltrating into road structures, reduced structural performance of pavement or damage to bridge structures, and surface scaling, in combination with freezing damage in winter, as well as water pollution. In addition, the deterioration of paved concrete road surface that occurs after the use of calcium chloride-based de-icing agent accelerates the development of visual problems with traffic structures. Therefore, the present study was performed to prepare an environment-friendly liquid de-icing agent through a reaction between waste organic acids and calcium-based by-products, which are industrial by-products, and to analyze the properties of the de-icing agent in order to evaluate its applicability to road facilities.

A study to apply phase change material(PCM) to rapid hardening cement paste forming semi-rigid pavement was carried out. The characteristics fresh and hardened paste were evaluated through the experiment for a total of 6 mixtures according to the cement type and the substitution of phase change material for acrylate. The fluidity by substituting phase change material for acrylate satisfied the target flow time of 10 to 13 seconds. In case of setting time, it was possible to secure the performance of rapid hardening cement by substituting phase change material, and if the substitution ratio over 60%, the initial set occurred 1 to 2 minutes faster than other mixtures. In case of compressive strength and bond strength, it showed similar strength characteristics with the plain mixture, and it satisfied both the target compressive and bonding strength of 36MPa and 2MPa. The mixture substituting phase change material showed higher resistance to chloride ion penetration than the mixture only using acrylate and the OPC level was insufficient. From the results of physical and mechanical performances of semi-rigid pavement cement paste, the phase change material substitution rate of 20% was effective in the range of this study.