To prepare weather-resistant modified silane acrylic resin coatings for an architectural purpose, tetrapolymers were synthesized by radical polymerization. 3-Methacryloxypropyltrimethoxysilane (MPTS) as a silicone monomer and n-butyl acrylate, methyl methacrylate, and n-butyl methacrylate as acrylic monomers were used. The composition of monomers was adjusted to fix the glass transition temperature of acrylic polymer for 20℃. The composition of MPTS in the synthesized polymer were varied from 10 wt% to 30 wt%. On the basis of synthesized resin amber paints were prepared and their physical properties and effects on weatherability were examined. The presence of MPTS in modified silane acrylic resins generally resulted in low molecular weight and broad molecular weight distribution, and also lowered the viscosity of the copolymers. The coated films prepared from these resins showed good and balanced properties in general. Adhesion to the substrate was outstanding in particular. Weatherability tests were carried out in three different types such as outdoor exposure, QUV, and SWO. The test results showed that the modified silane acrylic resins containing 30 wt% of MPTS had superior weathering properties.
To prepare weather-resistant silicone/acrylic resin coatings for an architectural purpose, tetrapolymers were synthesized by a radical polymerization. 3-Methacryloxypropyltrimethoxysilane (MPTS) as a silicone monomer and n-butyl acrylate, methyl methacrylate, and n-butyl methacrylate as acrylic monomers were used. The compositions of monomers were adjusted to fix the glass transition temperature of acrylic polymer for 20℃. The composition of MPTS in the synthesized polymer were varied from 10 wt% to 30 wt%. On the basis of synthesized resin amber paints were prepared and their physical properties and effects for weatherability were examined. The presence of MPTS in silicone/acrylic resins generally resulted in low molecular weight and broad molecular weight distribution, and also lowered the viscosity of the copolymers. The coated films prepared from these resins showed good and balanced properties in general. Adhesion to the substrate was outstanding in particular. Weatherability tests were carried out in three different types such as outdoor exposure, QUV, and SWO. The test results showed that the silicone/acrylic resins containing 30 wt% of MPTS had weather-resistant properties.
수도에서 흰둥멸구 저항성 유전자 Wb ph 1을 가지고 있는 것으로 알려진 N22와 Wb ph 2를 가지고 있는 것으로 알려진 ARC 10239에서 묘령별ㆍ얼자별로 흰등멸구 약충생존율의 차이를 조사한 결과는 다음과 같이 요약될 수 있다. 1) N 22와 ARC10239는 다 같이 묘령에 따라 약충생존율에 차이가 있었으며 그 경향은 품종에 따라 달랐다. ~circled1 N 22는 7일 묘부터 30일 묘까지 약충생존율이 매우 높고, 40일 묘에서 급격히 낮아지며, 생육후기에 다시 높아지는 경향을 보였다. ~circled2 ARC 10239는 7 일 묘에서 약충생존을이 매우낮고, 그 후 점차 높아지다가 40일 묘에서 다시 낮아져 생육후기까지 아주 낮은 경향을 보였다. 2) N22와 ARC10239는 다 같이 얼자간에 약충생존율의 차이가 있었고, 주간의 약충생존율이 낮은 묘령에서 얼자간 약충생존율의 차이가 적었으며, 얼자보다는 주간의 약충생존율이 낮은 경향을 보였다.