The permanent shut-down of Kori unit 1, the first nuclear power plant (NPP) in Korea, generates various radioactive waste. They are dry active waste (DAW), spent resin, concentrated waste, activated metals, etc. During normal operation of NPP, activated metals are rarely generated. The decommissioning of NPP, however, generates massive amount of metallic waste including activated metals and contaminated metals, while normal operation generates small amount of metallic waste. The reactor vessel and internals are relatively highly activated components in NPP. Since they are exposed to the high concentration of neutrons during the operation, their contains relatively high radioactive nuclides. They activation analysis is usually performed to understand the radiological inventory of the activated reactor vessel and internal. The results offer various important information including, radiological inventory, waste classification, etc. The impurities in the carbon steel and stainless steel have a great impact on the radiological inventory of the activated metals. The cobalt, nickel, niobium are primary elements that affects the activation analysis and waste classification. Especially, the cobalt, which transforms to 60Co, plays an important role. The 60Co, strong gamma emitter, affects the waste classification, safety analysis of decommissioning workers, and determination of segmentation and package plans. In this paper, effects of impurity concentration on activation analysis is studied. The expected impurity from various sources, including NUREG/CR-3474, commercial NPP data, etc, and effects will be demonstrated. Also, the comparison between results and international experiences will be followed.