Recently, hollow carbon spheres (HCS) have aroused great interests in the field of energy storage and conversion owing to their unique morphology, structure and other charming properties. Nevertheless, unsatisfactory electrical conductivity and relatively poor volumetric energy density caused by inevitable gaps between discrete carbon spheres greatly impede the practical application of HCS. In this work, for the first time we propose a novel dual-template strategy and successfully fabricate interconnected 3D hollow N-doped carbon network (HNCN) by a facile and scalable pyrolysis process. By systematical characterization and analysis, it can be found that HNCN is assembled by HCS and lots of mesoporous carbon. Compared to the counterparts, the obtained HNCN exhibits unique 3D interconnected architecture, larger specific surface area, hierarchical meso/macropore structure, higher structure defects, higher N doping amount and more optimized N configurations (especially for pyridinic-N and graphitic-N). As a result, these advantageous features endow HNCN with remarkably promoted electrochemical performance for supercapacitor and oxygen reduction reaction. Clearly, our proposed dual-template strategy provides a good guidance on overcoming the intrinsic shortcomings of HCS, which undoubtedly broadens their application in energy storage and conversion.

목적 : 본 연구는 국민건강영양조사 제7기(2016-2018) 원시자료를 이용하여, 녹내장에 영향을 미칠 수 요소 들과 그 연관성 정도를 파악하고자 하였다. 방법 : 녹내장 의사진단여부 및 만성질환에 응답한 만 30세 이상의 성인 총 5,244명을 대상으로, 녹내장에 영 향을 미칠 수 있는 신체활동과 만성질환 유병간의 기술통계 분석과 로지스틱회귀분석을 하였다. p<0.050인 경우 유의한 것으로 판단하였다. 결과 : 녹내장은 나이가 많아질수록 위험성이 높아지는 것을 알 수 있었다. 녹내장을 가지고 있는 사람의 신체 활동은 하루 중 앉아서 지내는 시간이 길고, 일주일에 근육운동을 하는 횟수가 많은 것으로 나타났다. 또한 변형 근로시간이 유의하게 많은 것으로 나타났다. 만성병과 관련하여서는 연령과 성별을 보정한 로지스틱회귀분석에서 이상지질혈증을 가지고 있는 사람들은 그렇지 않은 경우보다 녹내장의 발생 확률이 1.44배로 높아질 수 있는 것 으로 나타났다. 결론 : 본 연구는 녹내장 발병에 영향을 미치는 요인을 광범위하게 분석했다는 점에 의의가 있으며, 녹내장에 영향을 미칠 수 있는 생활 속 요인들을 파악함으로써 녹내장 발생 및 유병의 진행을 늦추는데 도움이 되고자 한다.

The major concern in the deep geological disposal of spent nuclear fuels include sulfide-induced corrosion and stress corrosion cracking of copper canisters. Sulfur diffusion into copper canisters may induce copper embrittlement by causing Cu2S particle formation along grain boundaries; these sulfide particles can act as crack initiation sites and eventually cause embrittlement. To prevent the formation of Cu2S along grain boundaries and sulfur-induced copper embrittlement, copper alloys are designed in this study. Alloying elements that can act as chemical anchors to suppress sulfur diffusion and the formation of Cu2S along grain boundaries are investigated based on the understanding of the microscopic mechanism of sulfur diffusion and Cu2S precipitation along grain boundaries. Copper alloy ingots are experimentally manufactured to validate the alloying elements. Microstructural analysis using scanning electron microscopy with energy dispersive spectroscopy demonstrates that Cu2S particles are not formed at grain boundaries but randomly distributed within grains in all the vacuum arc-melted Cu alloys (Cu-Si, Cu-Ag, and Cu-Zr). Further studies will be conducted to evaluate the mechanical and corrosion properties of the developed Cu alloys.

Different materials have been shown to "catalyze" carbon nanotube (CNT) growth in chemical vapor deposition (CVD) when they become nano-sized particles. Catalysts, which act as a kind of "seed" for CNT growth, show two types of behavior in the CVD method; precipitation of carbon atoms from the eutectic alloy forming a kind of alloy with carbon; the fact that the catalyst remains as a solid phase and forms a carbon surface layer during the CVD process. This study examines the relationship between the iron-group and non-iron-group catalyst types and the catalyst concentration and growth time of CVD-based CNT growth via emphasizing growth mechanisms. The novelty of this work is to compare and evaluate the effects of catalyst type, concentration, and growth time, which are three critical CVD parameters, on the final nanotube morphology. It was utilized five different catalysts ( Fe2O3, Fe3O4, Nb2O5, Au, and Pt), three different growth durations (3, 5, and 7 min), and three different catalyst concentrations (2, 4, and 6 wt%) to explore the morphological differences on CNT synthesis by CVD under the same process parameters. The results demonstrated that catalyst type is the most influential parameter in CVD-based CNT synthesis, while catalyst concentration and growth time are indispensable elements for the uniformity and small diameter in the final morphology.

Because of the massive development of nuclear power plants in China in recent years, China is facing the challenge of radioactive waste disposal. China has established complete regulatory requirements for radioactive waste disposal, but it also has encountered problems and challenges in low-level radioactive waste disposal in terms of management, selection of disposal facility sites, and implementation of a site selection plan. Three low-level radioactive waste disposal facilities that have been operated in China are described, and their activity limits, locations, and capacities are also outlined. The connotations of “regional” and “centralized” disposal policies are discussed in light of the characteristics of the radioactive waste. The characteristics and advantages of the regional and centralized disposal policies are compared. It is concluded that the regional disposal policy adopted in 1992 can no longer meet the current disposal needs, and China should adopt a combination of the two disposal policies to solve the problem of radioactive waste disposal.

The International Atomic Energy Agency (IAEA) entails independent decision-making for the safety supervision of civil nuclear facilities. To evaluate and review the safety of nuclear facilities, the national regulatory body usually consults independent institutions or external committees. Technical Support Organizations (TSOs) include national laboratories, research institutions, and consulting organizations. Support from professional organizations in other countries may also be required occasionally. Most of the world’s major nuclear power countries adopt an independent nuclear safety supervision model. Accordingly, China has continuously improved upon the construction of such a system by establishing the National Nuclear Safety Administration (NNSA) as the decision-making department for nuclear and radiation safety supervision, six regional safety supervision stations, the Nuclear and Radiation Safety Center (NSC), a nuclear safety expert committee, and the National Nuclear and Radiation Safety Supervision Technology R&D Base, which serves as the test, verification, and R&D platform for providing consultation and technical support. An R&D system, however, remains to be formed. Future endeavors must focus on improving the technical support capacity of these systems. As an enhancement from institutional independence to capability independence is necessary for ensuring the independence of China’s nuclear safety regulatory institution, its regulatory capacity must be improved in the future.

Technology for high-level-waste disposal employing a multibarrier concept using engineered and natural barrier in stable bedrock at 300–1,000 m depth is being commercialized as a safe, long-term isolation method for high-level waste, including spent nuclear fuel. Managing heat generated from waste is important for improving disposal efficiency; thus, research on efficient heat management is required. In this study, thermal management methods to maximize disposal efficiency in terms of the disposal area required were developed. They efficiently use the land in an environment, such as Korea, where the land area is small and the amount of waste is large. The thermal effects of engineered barriers and natural barriers in a high-level waste disposal repository were analyzed. The research status of thermal management for the main bedrocks of the repository, such as crystalline, clay, salt, and other rocks, were reviewed. Based on a characteristics analysis of various heat management approaches, the spent nuclear fuel cooling time, buffer bentonite thermal conductivity, and disposal container size were chosen as efficient heat management methods applicable in Korea. For each method, thermal analyses of the disposal repository were performed. Based on the results, the disposal efficiency was evaluated preliminarily. Necessary future research is suggested.

Soft magnetic powder materials are used throughout industries such as motors and power converters. When manufacturing Fe-based soft magnetic composites, the size and shape of the soft magnetic powder and the microstructure in the powder are closely related to the magnetic properties. In this study, Fe-Si-Al-P alloy powders were manufactured using various manufacturing process parameter sets, and the process parameters of the vacuum induction melt gas atomization process were set as melt temperature, atomization gas pressure, and gas flow rate. Process variable data that records are converted into 6 types of data for each powder recovery section. Process variable data that recorded minute changes were converted into 6 types of data and used as input variables. As output variables, a total of 6 types were designated by measuring the particle size, flowability, apparent density, and sphericity of the manufactured powders according to the process variable conditions. The sensitivity of the input and output variables was analyzed through the Pearson correlation coefficient, and a total of 6 powder characteristics were analyzed by artificial neural network model. The prediction results were compared with the results through linear regression analysis and response surface methodology, respectively.

The electrochemical behavior was investigated during the electrolysis of nickel oxide in LiCl-Li2O salt mixture at 650℃ by changing several components. The focus of this work is to improve anode design and shroud design to increase current densities. The tested components were ceramic anode shroud porosity, porosity size, anode geometry, anode material, and metallic porous anode shroud. The goal of these experiments was to optimize and improve the reduction process. The highest contributors to higher current densities were anode shroud porosity and anode geometry.