Mo-ODS alloys have excellent mechanical properties, including an improved recrystallization temperature, greater strength due to dispersed oxides, and the ability to suppress grain growth at high temperatures. In ODS alloys, the dispersed Y2O3 and added Ti form Y-Ti-O complex oxides, producing finer particles than those in the initial Y2O3. The complex oxides increase high-temperature stability and improve the mechanical properties of the alloy. In particular, the use of TiH2 powder, which is more brittle than conventional Ti, can enable the distribution of finer oxides than is possible with conventional Ti powder during milling. Moreover, dehydrogenation leads to a more refined powder size in the reduction process. This study investigated the refinement of Yi2Ti2O7 in a nano Mo-ODS alloy using TiH2. The alloy compositions were determined to be Mo-0.5Ti-0.5Yi2O3 and Mo-1.0Ti-0.5Yi2Oi2. The nano Mo-ODS alloys were fabricated using Ti and TiH2 to explore the effects of adding different forms of Ti. The sintered specimens were analyzed through X-ray diffraction for phase analysis, and the microstructure of the alloys was analyzed using scanning electron microscopy and transmission electron microscopy. Vickers hardness tests were conducted to determine the effect of the form of Ti added on the mechanical properties, and it was found that using TiHi2 effectively improved the mechanical properties.

In this study, a core-shell powder and sintered specimens using a mechanically alloyed (MAed) Ti-Mo powder fabricated through high-energy ball-milling are prepared. Analysis of sintering, microstructure, and mechanical properties confirms the applicability of the powder as a sputtering target material. To optimize the MAed Ti-Mo powder milling process, phase and elemental analyses of the powders are performed according to milling time. The results reveal that 20 h of milling time is the most suitable for the manufacturing process. Subsequently, the MAed Ti-Mo powder and MoO3 powder are milled using a 3-D mixer and heat-treated for hydrogen reduction to manufacture the core-shell powder. The reduced core-shell powder is transformed to sintered specimens through molding and sintering at 1300 and 1400oC. The sintering properties are analyzed through X-ray diffraction and scanning electron microscopy for phase and porosity analyses. Moreover, the microstructure of the powder is investigated through optical microscopy and electron probe microstructure analysis. The Ti-Mo core-shell sintered specimen is found to possess high density, uniform microstructure, and excellent hardness properties. These results indicate that the Ti-Mo core-shell sintered specimen has excellent sintering properties and is suitable as a sputtering target material.