Ion exchange resins are commonly employed in the treatment of liquid radioactive waste generated in nuclear power plants (NPP). The ion exchange resin used in NPP is a mixed-bed ion exchange resin known as IRN-150, which is of nuclear grade. This resin is a mixture of cation exchange resin and anion exchange resin. The cation exchange resin removes cationic radionuclides such as Cs and Co, while anion exchange resin handles anions (e.g., H14CO3 -), effectively purifying the liquid waste. Spent ion exchange resins (spent resin) containing C-14 are classified as low and intermediate level radioactive waste, and their radioactivity needs to be reduced as it exceeds the disposal limit regulated by law. Therefore, the microwave technology for the removal of C-14 from spent resin has been investigated. Previous studies have successfully developed a method for the effective removal of C-14 during the resin treatment process. However, it was observed that, in this process, functional groups in the resin were also removed, resulting in the generation of off-gases containing trimethylamine. These off-gases can dissolve in water from process, increasing its pH, which can subsequently hinder the recovery of C-14. In this study, we investigated the high-purity recovery of C-14 by adjusting the moisture content within the reactor following microwave treatment. Mock spent resins, consisting of 100 g of resin with HCO3 - ion-exchanged and 0, 25, or 50 g of deionized water, were subjected to microwave treatment for 40 or 60 minutes. Subsequently, the C-14 desorption efficiency of the mock spent resins was evaluated using an acid stripping process with H3PO4 solution. The functional group status of the mock spent resins was analyzed using 15N NMR spectroscopy. The results showed that the mock spent resins exhibited efficient C-14 recovery without significant functional group degradation. The highest C-14 desorption efficiency was achieved when 25 g of deionized water was used during microwave treatment.

The intermediate level spent resins waste generated from water purification for the the moderator and primary heat transport system during operaioin of heavy water reactor (HWR). Especially, moderator resins contain high level activity largely because of their C-14 content. So spent resins are considered as a problematirc solid waste and require special treatment to meet the waste acceptance criteria for a disposal site. Various methods have been studied for the treatment of spent resins which include thermal, destructive, and stripping methods. In the case of solidification methods, cement, bitument or organic polymers were suggested. In the 1990s, acid stripping using nitric acid and thermal treatment methods were actively investigated in Canada to remove C-14 nuclide from waste resin. In Japan, thermal distructive method was studied in the 1990s. Since 2005, KAERI developed acid stripping method using phosphate salt. However, acid stripping method are not suitable due to large amounts of 2nd waste containing acid solution with various nuclides. To solve this probelm, KAERI has been suggested the microwave treatment method for C-14 selective removal from waste resin in the 2010s. Pilot scale demonstration tests using radioactive waste resin generated from Wolsung unit 1 and unit 2 were successfully conducted and 95% of C-14 was selectively removed from the radioactive waste resin. In recent years, price of C-14 source is dramatically increased due to market growth of C-14 utilization and exclusive supply chain depending on China and Russia. High purity of C-14 were captured in HWR waste resin. Interest of C-14 recovery research from HWR waste resin is currently increased in Canada. In this study, microwave method is suggested to treat HWR waste resin with C-14 recovery process. Additionally, status of waste resin management and research trends of HWR waste resin treatment are introduced.

Mixed-bed ion exchange resin consist of anion exchange resin and cation exchange resin is used to treat liquid radioactive waste in nuclear power plants. C-14 from heavy water reactors (HWR) is adsorbed on the anion exchange resin and is considered intermediate-level radioactive waste. The total amount of radioactivity of C-14 in spent ion exchange resin exceeds the activity limits for the disposal facility. Therefore, it is necessary to reduce the radioactivity through pre-treatment. There are thermal and non-thermal methods for the treatment of spent ion exchange resin. However, destructive methods have the problem of emitting off-gas containing radionuclides. To solve this challenge, various methods have been developed such as acid stripping, PLO process, activity stripping, thermal treatment and others. In this study, spent ion exchange resin (spent resin) was treated using microwave. The reaction characteristics of the resin to microwave were used to selectively remove the C-14 on the functional groups. Simulated spent anion exchange resin and spent resin from Wolseong NPP were treated with the microwave method, and the desorption rate was over 95%. An integrated process system of 1 kg/batch was built to produce operating data. After the operation of the process, characterization and evaluation of post-treatment for condensate water and adsorbent used in the process were performed. When the process system was applied to treat simulated spent resin and real spent resin, both showed a desorption rated of more than 97%. It means that the C-14 was successfully removed from the radioactive spent resin.

In NPP (nuclear power plant), boric acid is used as a neutron absorbent. So radioactive boric acid waste are generated from various waste streams such as discharge or leakage of reactor coolant water, floor drains, drainage of equipment for operation or maintenance, reactor letdown flows and etc. Depending on KHNP, 20,015 drum (200 L drum) of concentrated boric acid waste were stored in KOREA NPP until 2019. In previous study, our group suggested the waste up-cycling process synthesizing B4C neutron absorber using boric acid waste and activated carbon waste to innovatively reduce radioactive wastes. Radioactive activated carbon waste was utilized in off gas treatment system of NPP to capture nuclide such as I-131, C-14 and H-3. Activated carbon waste is treated as low-level radioactive waste and pre-treatment system for removing nuclide from the activated carbon waste is needed to use B4C up-cycling process. In this study, microwave treatment system is suggested to treat the activated carbon waste. Activated carbon waste was exposed to microwave for a few minutes and temperature of the waste was dramatically increased over 400°C. Nuclide in the activated carbon waste were selectively removed from the waste without massive production of secondary off gas waste.

Inorganic and organic ion exchange materials were generally applied to liquid processes in nuclear reactor. In the case of heavy-water reactor (HWR), zeolite, active carbon, anion resin, and cation resin were used to treat liquid processes such as reactor primary coolant cleanup and liquid radioactive waste management system. Then, used ion exchangers were stored at storage tanks. Various kinds of nuclides were adsorbed in ion exchange materials. Especially, C-14, long half-life nuclide, was highly concentrated in anion resin, and waste resin was treated as intermediated level radioactive waste (ILW). Thermal and non-thermal methods such as pyrolysis, incineration, catalytic extraction, acid digestion, and wet oxidation have been studied for treating spent resin. However, destructive methods are not suitable due to massive off gas waste containing radioactive species. To solve this problem, various kinds of processes were developed such as acid stripping, PLO process, activity stripping, thermal treatment, and etc. In this study, microwave method is suggested to treat HWR waste resin. C-14 nuclide was selectively removed from waste resin without decomposition of main structure in waste resin. Radioactive waste resin generated from Wolsung HWR unit 1 and unit 2 was treated using microwave method and 95% of C-14 was successfully removed from the radioactive waste resin.

사용후핵연료의 효율적 관리를 위하여 한국원자력연구원에서 수행 중인 파이로 공정으로부터 발생되는 폐기물 처리기술에 대한 최근 연구동향을 종합적으로 고찰하였다. 파이로 폐기물 처리기술은 처분 대상 폐기물의 감용 및 포장, 저장과 최종 처분에 적합한 고화체 제조를 목표로 하고 있다. 한국원자력연구원에서 수행 중인 파이로 폐기물 처리 기술개발 접근 방향은 공정 흐름으로부터 발생한 폐기물내 주요 핵종들을 분리하고 회수한 물질 등을 재사용함으로서 폐기물 발생량을 최소로 하며 동시에 분리한 핵종을 별도로 고화처리하는 것이다. 폐기물 처리 주요 기술 특성은 먼저 전해환원용 원료물질 제조를 위하여 전처리 고온 열처리 공정을 사용하며, LiCl 과 LiCl-KCl 염으로부터 핵종을 분리하고 회수염의 재사용 및 핵종 함유량을 증대시킨 최종 고화체 제조 기술을 개발하는 것이다. 따라서 실험실 규모 실험 결과를 토대로 최근에는 공정 용량 증대를 위한 자료 확보를 목적으로 공학규모 시험을 수행 중에 있다.