Environmental pollution remains a considerable health risk source all over the world; however, hazards are usually higher in developing countries. Iraq has long been suffering from the problem of pollution and how to treat pollution. Photocatalytic degradation has turned out to be most productive process for dye degradation. In this investigation, Rhodamine B (RhB), dye has been selected for degradation under visible light illumination. To address this issue, we fabricate erbium trioxide nanoparticles (Er2O3/NPs). Erbium trioxide nanoparticles are prepared and utilized for photo-catalytic degradation. The characterization of Er2O3/NPs is described and confirmed by utilizing of XRD (X-ray diffraction) and SEM (Scanning Electron Microscopy). The average size of Er2O3 nanoparticles is observed to be 16.00 nm. Er2O3/NPs is investigated for its ability of photo-catalytic degradation through certain selected parameters such as concentration and time. The methodological results show that the synthesized Er2O3/NPs is a good photo-catalytic for Rhodamine degradation.
Intensive Monitoring Survey of Nearby Galaxies (IMSNG) is a high cadence observation program monitoring nearby galaxies with high probabilities of hosting supernovae (SNe). IMSNG aims to constrain the SN explosion mechanism by inferring sizes of SN progenitor systems through the detection of the shock-heated emission that lasts less than a few days after the SN explosion. To catch the signal, IMSNG utilizes a network of 0.5-m to 1-m class telescopes around the world and monitors the images of 60 nearby galaxies at distances D < 50 Mpc to a cadence as short as a few hours. The target galaxies are bright in near-ultraviolet (NUV) with MNUV < - 18.4 AB mag and have high probabilities of hosting SNe (0.06 SN yr-1 per galaxy). With this strategy, we expect to detect the early light curves of 3.4 SNe per year to a depth of R 19:5 mag, enabling us to detect the shock-heated emission from a progenitor star with a radius as small as 0.1 R. The accumulated data will be also useful for studying faint features around the target galaxies and other science projects. So far, 18 SNe have occurred in our target fields (16 in IMSNG galaxies) over 5 years, confirming our SN rate estimate of 0.06 SN yr-1 per galaxy.
In this study, an empirical relationship between the energy band gap of multi-walled carbon nanotubes (MWCNTs) and synthesis parameters in a chemical vapor deposition (CVD) reactor using factorial design of experiment was established. A bimetallic (Fe-Ni) catalyst supported on CaCO3 was synthesized via wet impregnation technique and used for MWCNT growth. The effects of synthesis parameters such as temperature, time, acetylene flow rate, and argon carrier gas flow rate on the MWCNTs energy gap, yield, and aspect ratio were investigated. The as-prepared supported bimetallic catalyst and the MWCNTs were characterized for their morphologies, microstructures, elemental composition, thermal profiles and surface areas by high-resolution scanning electron microscope, high resolution transmission electron microscope, energy dispersive X-ray spectroscopy, thermal gravimetry analysis and Brunauer-Emmett-Teller. A regression model was developed to establish the relationship between band gap energy, MWCNTs yield and aspect ratio. The results revealed that the optimum conditions to obtain high yield and quality MWCNTs of 159.9% were: temperature (700ºC), time (55 min), argon flow rate (230.37 mL min–1) and acetylene flow rate (150 mL min–1) respectively. The developed regression models demonstrated that the estimated values for the three response variables; energy gap, yield and aspect ratio, were 0.246 eV, 557.64 and 0.82. The regression models showed that the energy band gap, yield, and aspect ratio of the MWCNTs were largely influenced by the synthesis parameters and can be controlled in a CVD reactor.
We investigate two abnormal CME-Storm pairs that occurred on 2014 September 10 - 12 and 2015 March 15 - 17, respectively. The first one was a moderate geomagnetic storm (Dstmin -75 nT) driven by the X1.6 high speed flare-associated CME (1267 km s−1) in AR 12158 (N14E02) near solar disk center. The other was a very intense geomagnetic storm (Dstmin -223 nT) caused by a CME with moderate speed (719 km s−1) and associated with a filament eruption accompanied by a weak flare (C9.1) in AR 12297 (S17W38). Both CMEs have large direction parameters facing the Earth and southward magnetic field orientation in their solar source region. In this study, we inspect the structure of Interplanetary Flux Ropes (IFRs) at the Earth estimated by using the torus fitting technique assuming self-similar expansion. As results, we find that the moderate storm on 2014 September 12 was caused by small-scale southward magnetic fields in the sheath region ahead of the IFR. The Earth traversed the portion of the IFR where only the northward fields are observed. Meanwhile, in case of the 2015 March 17 storm, our IFR analysis revealed that the Earth passed the very portion where only the southward magnetic fields are observed throughout the passage. The resultant southward magnetic field with long- duration is the main cause of the intense storm. We suggest that 3D magnetic field geometry of an IFR at the IFR-Earth encounter is important and the strength of a geomagnetic storm is strongly affected by the relative location of the Earth with respect to the IFR structure.
We report a spatial uctuation analysis of the sky brightness in the near-infrared from observations towards the north ecliptic pole (NEP) by AKARI at 2.4 and 3.2 μm. As a follow up study of our previous work on the Monitor eld of AKARI, we used NEP deep survey data, which covered a circular area of about 0.4 square degrees, in order to extend uctuation analysis at angular scales up to 1000". After pre-processing, additional correction procedures were done to correct time varying components and instrumental effects such as MUXbleed. To remove resolved objects, we applied 2α clipping and point spread function (PSF) subtraction. We finally obtained mosaicked images which can be used for the study of various diffuse emissions in the near-infrared sky and found that there are spatial structures in the mosaicked images using a power spectrum analysis.
Polarbear is a ground-based experiment located in the Atacama desert of northern Chile. The experiment is designed to measure the Cosmic Microwave Background B-mode polarization at several arcminute resolution. The CMB B-mode polarization on degree angular scales is a unique signature of primordial gravitational waves from cosmic in ation and B-mode signal on sub-degree scales is induced by the gravitational lensing from large-scale structure. Science observations began in early 2012 with an array of 1,274 polarization sensitive antenna-couple Transition Edge Sensor (TES) bolometers at 150 GHz. We published the first CMB-only measurement of the B-mode polarization on sub-degree scales induced by gravitational lensing in December 2013 followed by the first measurement of the B-mode power spectrum on those scales in March 2014. In this proceedings, we review the physics of CMB B-modes and then describe the Polarbear experiment, observations, and recent results.
Since Montreal protocol in1989 designated MB(methyl bromide) as ozone depleting chemicals, IPPC(International Plant Protection Convention) has adopted replacing the MB with alternative chemical and reducing the rate of MB use in plant quarantine in 2008. Pineapples are one of the most frequently fumigated imported fruit with MB in Korea. However, there was no technically available replacement. Therefore, we evaluated phosphine(PH3) fumigation as alternative to MB in applying pineapples.
In the preliminary test, PH3 gas in 12L desicators to calculate ranged to 0.1 from 2g/m3 was tested at 2 and 24hr exposure to target pest, citrus mealy bug(CMB, Planococcus citri). All different of stage of CMB was shown 100% mortality when 2g/m3 of PH3 applied for 24hrs at 8℃. To confirm studies designed in 0.5m3 fumigation chamber, all egg, nymph and adult stages of CMB was killed completely and there wasn’t any phytotoxic and quality damages on pineapples for 2 weeks post-fumigation periods at 8℃. In terms of commercial use, further commercial research will need to be carry out in cooperation with importers and fumigators.
We report a search for fluctuations of the sky brightness toward the North Ecliptic Pole with AKARI, at 2.4, 3.2, and 4.1 μm . The stacked images with a diameter of 10 arcminutes of the AKARI-Monitor Field show a spatial structure on the scale of a few hundred arcseconds. A power spectrum analysis shows that there is a significant excess fluctuation at angular scales larger than 100 arcseconds that cannot be explained by zodiacal light, diffuse Galactic light, shot noise of faint galaxies, or clustering of low-redshift galaxies. These findings indicate that the detected fluctuation could be attributed to the first stars of the universe, i.e., Population III stars.
We present the properties of dust and the near-infrared spectral features in nearby early-type galaxies. The properties of dust are obtained from the AKARI far-infrared all-sky survey diffuse map. The AKARI/IRC is used for the near-infrared spectra. We improve spectral data with the new dark subtraction method on the basis of the knowledge acquired in our laboratory experiments of the engineering-model detector for the IRC. We have succeeded in fitting the continuum by a power-law function and detecting CO and SiO absorption features in early-type galaxy spectra. Comparing the properties of dust and near-infrared spectral features, we find that the power-law slope depends on dust temperature, but not on the dust mass, which suggests that low-luminosity AGNs may contribute to the changes in the power-law slope and dust temperature.
With AKARI, we carried out near-infrared spectroscopy of the nearby barred spiral galaxy, NGC 1097, categorized as Seyfert 1 with a circumnuclear starburst ring. Our observations mapped the galactic center region. As a result, we obtain the spatial distributions of the polycyclic aromatic hydrocarbon 3.3μm and the aliphatic hydrocarbon 3.4−3.6 μm emission. The former is detected from all the observed regions and the latter is enhanced near the bar connecting the ring with the nucleus. In addition, we detect absorption features due to H2O ice and CO/SiO at the ring and the galactic center, while we detect the hydrogen recombination line Brα only from the ring. Hence the observed spectra change dramatically within the central 1 kpc region.
The absorption features due to interstellar ices, especially H2O and CO2 ices, provide us with crucial information on present and past interstellar environments, and thus the evolutionary histories of galaxies. Before AKARI, however, few detections of ices were reported for nearby galaxies. The AKARI's unique capability of near-infrared spectroscopy with high sensitivity enables us to systematically study ices in nearby galaxies. Thus we have explored many near-infrared spectra ( 2.5−5μm ) of the 211 pointed observations, searching for the absorption features of ices. As a result, out of 122 nearby galaxies, we have significantly detected H2O ice from 36 galaxies and CO2 ice from 9 galaxies. It is notable that the ices are detected not only in late-type galaxies but also in early-type galaxies. We find that CO2 ice is more compactly distributed near the galactic center than H2O ice. Finally, we suggest that the gas density of a molecular cloud and UV radiation may be important factors to determine the abundance of ices.
Among the AKARI all-sky survey data, the 9 μm diffuse map is crucial to study the polycyclic aromatic hydrocarbon (PAH) emission features on large spatial scales, while the 18 μm map is useful to trace hot dust emission. To utilize these advantages, we have improved the AKARI mid-infrared (MIR) all-sky survey diffuse maps. For example, we have established special methods to remove the effects of the ionizing radiation in the South Atlantic Anomaly (SAA) and of the scattered light from the moon. Using improved diffuse map data, we study the properties of PAHs and dust in the Galactic center region associated with high-energy phenomena.