Evaporative emission generated through the fuel supply system of a gasoline automobile is prevented into the atmosphere through an activated carbon canister system. In this study, the oxygen functional group of activated carbon was controlled using a simple gas phase treatment to improve evaporative emission reduction performance, and the adsorption/desorption performance of evaporative emissions was evaluated according to microwave heating conditions. Microwave heating was used to remove the oxygen functional group of the activated carbon efficiently. Microwave heating was found to remove oxygen functional groups in a short treatment time (1–7 min). Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, and scanning electron microscope–energy-dispersive X-ray spectroscopy were employed to investigate modifying the oxygen functional group of the activated carbon. Using N2/ 77K adsorption/desorption isotherm, the textural properties of the activated carbon according to microwave heating conditions were examined. The Brunauer–Emmett–Teller (BET) equation was used to calculate the specific surface area of the activated carbon, and the Dubinin–Radushkevich (DR) equation was used to calculate the micropore volume of activated carbon. Microwave heating effectively increased the butane working capacity, which is the neat adsorption capacity of activated carbon, from 7.12 g/100 ml to a maximum of 8.04 g/100 ml.

In this work, the correlation between the pore characteristics of activated carbon (AC) and the adsorption/desorption characteristics of evaporated fuel was studied. AC was prepared by various physical re-activation methods using coconut-derived commercial AC. Pore characteristics of the re-activated AC were investigated using N2/ 77 K adsorption isotherms. The structural characteristics of the AC were observed by X-ray diffraction and Raman spectroscopy. The butane working capacity was observed according to ASTM D5228. From the results, the specific surface area and total pore volume of the ACs were determined to be 1380–2040 m2/g and 0.60–0.96 cm3/g, respectively. It was also observed that various pore size distributions were found to be dependent on the functions of the activation method and time. A close relationship between butane activity/ retentivity and micropore/mesopore volumes was found. In addition, it was inferred that the volume fraction of micropores and sub-mesopores with diameters between 1.5 and 3.0 nm primarily controls butane activity.

In this study, we prepared ACFs with a high specific surface area from various precursors (rayon, pitch, and oxidized polyacrylonitrile-based fibers) by a steam-activation technique and investigated the effects of the micropore and mesopore fraction on 2-CEES adsorption behaviors. The activation time was precisely controlled so that the activation yield was in the range of 35–40% to ensure the mechanical properties of the ACFs. The N2 adsorption isotherm characteristics at 77K were confirmed by Brunauer–Emmett–Teller, Barrett–Joyner–Halenda and non-local density functional theory equations. The adsorption capacities of the ACF were measured by breakthrough experiments in the gas phase (750 μg/mL of 2-CEES in N2 flow). The removal efficiency of the ACFs was evaluated and compared with that of AC. From the results, specific surface areas and total pore volume of the ACF were determined to be 1380–1670 m2/g and 0.61–0.82 cm3/g, respectively. It was also observed that various pore characteristics of ACF were found to be dependent on crystallite structure of each precursor. The break through time (C/C0 = 0.10) was in the order of Oxi-Pan-H-9-2 < Saratoga AC < Rayon-H-9-3 < Pitch-H-9-4. This indicates that 2-CEES adsorption capacity could be a function not only of specific surface area or total pore volume, but also of sub-mesopore volume fraction in the range of 1.5–2.5 nm of adsorbents.

In this study, activated carbon with well-developed mesopores was fabricated using kenaf short fibers as a representative biomass. Concentrated phosphoric acid was selected as an activation agent to create highly developed porous structures, and pore development was observed to occur in relation to the weight ratio of phosphoric acid and kenaf. The pore characteristics of the kenaf-based activated carbon were determined using the N2/ 77K adsorption isotherm, and its microcrystalline structure was analyzed using X-ray diffraction. The highest specific surface area (1570 m2/g) was observed when the weight ratio of phosphoric acid to kenaf was 3:1, and the highest mesopore fraction (74%) was observed at 4:1. The carbonization yield was 45–35%, which is higher than that of commercial activated carbon. The production of porous carbon material by this method offers high potential for application because it can be controlled over a wide range of average pore diameter from 2.48 to 5.44 nm.