An effective cleaning method for Ni removal in Ni-induced lateral crystallization(Ni-MILC) poly-Si TFTs and their electrical properties are investigated. The HCN cleaning method is effective for removal of Ni on the crystallized Si surface, while the nitric acid treatment results decrease by almost two orders of magnitude in the Ni concentration due to effective removal of diffused Ni mainly in the poly-Si grain boundary regions. Using the HCN cleaning method after the nitric acid treatment, re-adsorbed Ni on the Si surfaces is effectively removed by the formation of Ni-cyanide complexions. After the cleaning process, important electrical properties are improved, e.g., the leakage current density from 9.43 × 10−12 to 3.43 × 10−12 A and the subthreshold swing values from 1.37 to 0.67 mV/dec.
Multiple galvanized steel and aluminium alloy sheets were joined by self-piercing rivet(SPR) and hybrid joining(SPR + adhesive bonding). In this study, tensile-shear load and fatigue properties of multi-layer SPR and hybrid joints were investigated. Moreover, tensile-shear deformation behavior of the joints under different specimen configurations was investigated. Depending on the specimen configurations either top sheet tearing failure mode or rivet tail pull-out failure mode was observed during the tensile-shear tests. The top sheet tearing failure mode resulted in low maximum tensile-shear load, but it led to larger displacement value as compared to that in the tail pull-out failure mode. Maximum tensile-shear load of hybrid joints was about four times higher than that of SPR joints. Also, fatigue limit of hybrid joints was about two times higher than that of SPR joints.
Membrane bioreactors (MBRs) have big issue on high aeration energy. In this study, reciprocation of membrane was adapted to mitigate membrane fouling. Inertial force induced by reciprocation removed foulants from membrane surface. Pilot plant with capacity of 1,100 m³/day was operated for 8 months in Singapore. The result showed stable trans membrane pressure (TMP) and low permeate turbidity below 0.1 NTU at 25 LMH. It also showed 60 times less energy consumption than conventional MBR. Low dissolved oxygen in membrane tank resulted in higher nitrogen removal. Long-term reciprocation requires very strong membrane modules. Braid reinforced membrane and its modules were optimized to reciprocation. The evaluation of them after the operation showed there was no change in all their properties.
Polysulfone 재질의 다공성 평판막 및 실관막에 키토산 피막층을 형성시킨 후 반응성 염료인 Cibacron Blue 3GA를 고정화시켜 human serum albumin(HSA)의 결합용량이 최대 70 μg/cm2인 단백질 친화성 막을 제조하였다. 친화성 평판막 모듈을 대상으로 HSA에 대한 용출 크로마토그래피 실험을 수행하여 eluent 용액의 최적 환경조건을 결정하였는바, 1M KCl이 첨가된 농도 0.06 M, pH 10의 universal buffer를 eluent로 사용했을 때 리간드와 결합된 단백질의 용출이 가장 우수하였다. 친화성 평판막 및 실관막 모듈을 대상으로 HSA의 전열 크로마토그래피 실험을 수행하여 단백질에 대한 동적 결합용량을 측정하였다. 이 결과 동적 결합용량은 평판막 모듈의 경우에는 loading 용액의 유량과 HSA의 농도가 증가함에 따라 평형 결합용량 값으로부터 크게 감소하였으나, 실관막 모듈의 경우에는 loading 용액의 유량과 HSA의 농도에 관계없이 항상 평형 결합용량 수준을 유지하였는바, 따라서 실관막 모듈이 평판막 모듈보다 단백질 친화성 크로마토그래피 분리관으로서 더 효과적이었다