Domestic commercial low- and intermediate-level radioactive waste storage containers are manufactured using 1.2 mm thick cold-rolled steel sheets, and the outer surface is coated with a thin layer of primer of 10~36 μm. However, the outer surface of the primer of the container may be damaged due to physical friction, such as acceleration, resonance, and vibration during transportation. As a result, exposed steel surfaces undergo accelerated corrosion, reducing the overall durability of the container. The integrity of storage containers is directly related to the safety of workers. Therefore, the development of storage containers with enhanced durability is necessary. This paper provides an analysis of mechanical properties related to the durability of WC (tungsten carbide)-based coating materials for developing low- and intermediate-level radioactive waste storage containers. Three different WC-based coating specimens with varied composition ratios were prepared using HVOF (high-velocity oxy-fuel) technique. These different specimens (namely WC-85, WC-73, and WC-66) were uniformly deposited on cold-rolled steel surfaces ensuring a constant thickness of 250 μm. In this work, the mechanical properties of the three different WCbased coaitng materials evaluated from the viewpoints of microstructure, hardness, adheision force between substrate and coating material, and wear resistance. The cross-sectional SEM-EDS (Scanning Electron Microscope-Energy Dispersive X-ray Spectroscopy) images revealed that elements W (tungsten), C (carbon), Ni (nickel), and Cr (chromium) were uniformly distributed within the each coating layers which was approximately 250 μm thick. The average hardness values of HWC-85 and HWC-73 were found to be 1,091 Hv (Vickers Hardness) and 1,083 Hv, respectively, while the HWC-66 exhibited relatively lower hardness value of 883 Hv. This indicates that a higher WC content results in increased hardness. Adhesion force between and substrates and coating materials exceeded 60 MPa for all specimens, however, there were no significant differences observed based on the tungsten carbide content. Furthermore, a taber-type abrasion tester was used for conducting abrasion resistance tests under specific conditions including an H-18 load weight at 1,000 g with rotational speed set at 60 RPM. The abrasion resistance tests were performed under ambient temperatures (RT: 23±2°C) as well as relative humidity levels (RH: 50±10%). Currently, the ongoing abrasion resistance tests will include some results in this study.
This study focuses on the development of coatings designed for storage containers used in the management of radioactive waste. The primary objective is to enhance the shielding performance of these containers against either gamma or neutron radiation. Shielding against these types of radiation is essential to ensure the safety of personnel and the environment. In this study, tungsten and boron cabide coating specimens were manufactured using the HVOF (High-Velocity Oxy Fuel) technuqe. These coatings act as an additional layer of protection for the storage containers, effectively absorbing and attenuating gamma and neutron radiation. The fabricated tungsten and boron carbide coating specimens were evaluated using two different testing methods. The first experiment evaluates the effectiveness of a radiation shielding coating on cold-rolled steel surfaces, achieved by applying a mixture of WC (Tungsten Carbide) powders. WC-based coating specimens, featuring different ratios, were prepared and preliminarily assessed for their radiation shielding capabilities. In the gamma-ray shielding test, Cs-137 was utilized as the radiation source. The coating thickness remained constant at 250 μm. Based on the test results, the attenuation ratio and shielding rate for each coated specimen were calculated. It was observed that the gammaray shielding rate exhibited relatively higher shielding performance as the WC content increased. This observation aligns with our findings from the gamma-ray shielding test and underscores the potential benefits of increasing the tungsten content in the coating. In the second experiment, a neutron shielding material was created by applying a 100 μm-thick layer of B4C (Boron Carbide) onto 316SS. The thermal neutron (AmBe) shielding test results demonstrated an approximate shielding rate of 27%. The thermal neutron shielding rate was confirmed to exceed 99.9% in the 1.5 cm thick SiC+B4C bulk plate. This indicates a significant reduction in required volume. This study establishes that these coatings enhance the gamma-ray and neutron shielding effectiveness of storage containers designed for managing radioactive waste. In the future, we plan to conduct a comparative evaluation of the radiation shielding properties to optimize the coating conditions and ensure optimal shielding effectiveness.
Poly(vinyl chloride)-g-poly(styrene sulfonic acid) (PVC-g-PSSA) 가지형 공중합체를 합성한 후, 이를 이용하여 80℃에서 열적으로 환원하여 은 나노입자를 제조하였다. 반응 시간을 바꿈에 따라 다양한 구조의 은 나노입자를 제조하는데 성공하였다. 1시간 정도의 짧은 반응 시간에서는 가지형 공중합체의 미세 상분리 구조를 크게 변화시키지 않고 5 nm 크기의 작은 은 나노입자가 생성되었다. 5시간 정도의 중간 반응 시간에서는 30 내지 50 nm 정도의 크기를 갖는 은 나노입자가 생성되었다. 18시간 정도의 긴 반응 시간에서는, 은입자가 뭉친 허리케인 모양의 은 집합체가 관찰되었다.
Radioprotection is of practical importance for the normal tissues of tumor patients subject to radiotherapy, people with planned or accidental exposure to radiation, and the public and radiation workers. Since oxygen enhances radiation - induced biologica
Background : Despite the presence of various bioactive compounds in ginseng, there is lack of study on the variations of bioactive compounds in ginseng according to the cultivation of soil and the applied fertilizer types (or amount). Therefore, this study aims to examine the variations of 37 fatty acids (FA) and 8 vitamin E (Vit-E) vitamers in 6-year-old ginseng root cultivated in different soil types with different fertilizers regimes. Methods and Results : The profiling of 37 FAs and 8 Vit-E vitamers in 6-year-old ginseng roots was measured by gas chromatography coupled with a flame ionization detector, and then these results were statistically analyzed with chemometrics. The FA and Vit-E content in ginseng roots varied significantly with respect to soil cultivation conditions due to organic fertilizer types and amounts used. Unsaturated FA in ginseng is approximately 2.7 fold higher than the saturated FA. Linoleic, palmitic, and oleic acids were the most abundant FAs found in the ginseng roots. Also, the major Vit-E vitamer found in ginseng root is α -tocopherol. In particular, the application of rice straw compost or food waste fertilizer was increased to create nutritionally-desirable FAs and bioactive Vit-E in ginseng root. In addition, phytonutrient profiling coupled with chemometrics can be used to discriminate the cultivation conditions of ginseng. Conclusion : This preliminary study extends our understanding about the variations of FA and Vit-E in ginseng root depending on cultivation conditions. Hence, these results can be useful as basic information for reliable ginseng production containing high amounts of phytonutrients in a paddy-converted field.