Nuclear facilities present the important task related to the migration and retention of radioactive contaminants such as cesium (Cs), strontium (Sr), and cobalt (Co) for unexpected events in various environmental conditions. The distribution coefficient (Kd) is important factor for understanding these contaminants mobility, influenced by environmental variables. This study focusses the prediction of Kd values for radionuclides within solid phase groups through the application of machine-learning models trained on experimental data and open source data from Japan atomic energy agency. Three machine-learning models, such as the convolutional neural network, artificial neural network, and random forest, were trained for prediction model of the distribution coefficient (Kd). Fourteen input variables drawn from the database and experimental data, including parameters such as initial concentration, solid-phase characteristics, and solution conditions, served as the basis for model training. To enhance model performance, these variables underwent preprocessing steps involving normalization and log transformation. The performances of the models were evaluated using the coefficient of determination. These results showed that the environmental media, initial radionuclide concentration, solid phase properties, and solution conditions were significant variables for Kd prediction. These models accurately predict Kd values for different environmental conditions and can assess the environmental risk by analyzing the behavior of radionuclides in solid phase groups. The results of this study can improve safety analyses and longterm risk assessments related to waste disposal and prevent potential hazards and sources of contamination in the surrounding environment.

Radioactive contaminants, such as 137Cs, are a significant concern for long-term storage of nuclear waste. Migration and retention of these contaminants in various environmental media can pose a risk to the surrounding environment. The distribution coefficient (Kd) is a critical parameter for assessing the behavior of these contaminants and can introduce significant errors in predicting migration and remediation options. Accurate prediction of Kd values is essential to assess the behavior of radioactive contaminants and to ensure environmental safety. In this study, we present machine learning models based on the Japan Atomic Energy Agency Sorption Database (JAEA-SDB) to predict Kd values for Cs in soils. We used three different machine learning models, namely the random forest (RF), artificial neural network (ANN), and convolutional neural network (CNN), to predict Kd values. The models were trained on 14 input variables from the JAEA-SDB, including factors such as Cs concentration, solid phase properties, and solution conditions which are preprocessed by normalization and log transformation. We evaluated the performance of our models using the coefficient of determination (R2) value. The RF, ANN, and CNN models achieved R2 values of over 0.97, 0.86, and 0.88, respectively. Additionally, we analyzed the variable importance of RF using out-of-bag (OOB) and CNN with an attention module. Our results showed that the initial radionuclide concentration and properties of solid phase were important variables for Kd prediction. Our machine learning models provide accurate predictions of Kd values for different soil conditions. The Kd values predicted by our models can be used to assess the behavior of radioactive contaminants in various environmental media. This can help in predicting the potential migration and retention of contaminants in soils and the selection of appropriate site remediation options. Our study provides a reliable and efficient method for predicting Kd values that can be used in environmental risk assessment and waste management.