During the decommissioning of nuclear power plant (NPP), massive amount of concrete wastes is generated, which are non-radioactive and radioactive. The concrete is a representative construction material which affords reliable structural stability, good formability, and trustful integrity. Also, its reasonable neutron absorbing property allows the various application for many components, including building construction material, bio-shield concrete, etc. Due to the noted aspects of concrete, the radiological concrete characterization is classified as an important process for development of effective strategy for concrete management, in terms of process management and financial control during the decommissioning. The characterization of bio-shield concrete is important in waste management. The understanding and characterization of activation depth is essential for the determination of waste management strategy, classification of bio-shield concrete, and process development of decommissioning. On the other hand, concrete for construction application requires the evaluation of surface contamination of them. The concrete for containment building and its structure is rarely activated, but surface contaminated. In this paper, the reactor data from representative PWR reactors in the US is studied. The experience on Yankee Rowe, Maine Yankee, and Connecticut Yankee NPPs are systematically studied. The Yankee Rowe was a 4-loop PWR of Westinghouse design with 185 MWe. The Main Yankee was a 3- loop PWR of Combustion Engineering design with 864 MWe. The Connecticut Yankee was a 4-loop Westinghouse type with 560 MWe. The characterization studies on bio-shield concrete will be discussed in this paper, including activation depth, primary nuclides, etc.

During the normal operation boron concentrates and spent resins are generated. The boron concentrates are treated by concentrated waste drying system (CWDS) and results in fine powder form. The solidification or application of high integrity container (HIC) is required for the disposal of the dried boron concentrates. The spent resin is stored in storage tank after the water treatment. The spent resin also requires solidification or application of HIC to satisfy the waste acceptance criteria (WAC) in Korea. The solidification process requires periodic validation. The repeated validation and complicated process hesitates the practical application. The application of HIC offers various advantages, including flexible free standing water requirement, higher waste loading compared to solidification, and simple process. The polymer concrete (PC), which is a primary component for PC-HIC exhibits good material stability. The expected transportation mechanism of nuclide in the PC-HIC are 1) diffusion by concentration, 2) permeation by pressure, and 3) capillary suction when considering the disposal condition. Since the PC-HIC effectively prevents the intrusion of neighboring water and volume of free standing water is lower than 1%, it seems that diffusion by concentration is the primary transportation mechanism. In this study, the property of PC is investigated based on Cl ion diffusion test to evaluate the material reliability. The results indicate that PC exhibits superior stability compared to ordinary portland cement. In addition, the reliable life time of PC is estimated base on the element transportation phenomena.

The permanent shut-down of Kori unit 1, the first nuclear power plant (NPP) in Korea, generates various radioactive waste. They are dry active waste (DAW), spent resin, concentrated waste, activated metals, etc. During normal operation of NPP, activated metals are rarely generated. The decommissioning of NPP, however, generates massive amount of metallic waste including activated metals and contaminated metals, while normal operation generates small amount of metallic waste. The reactor vessel and internals are relatively highly activated components in NPP. Since they are exposed to the high concentration of neutrons during the operation, their contains relatively high radioactive nuclides. They activation analysis is usually performed to understand the radiological inventory of the activated reactor vessel and internal. The results offer various important information including, radiological inventory, waste classification, etc. The impurities in the carbon steel and stainless steel have a great impact on the radiological inventory of the activated metals. The cobalt, nickel, niobium are primary elements that affects the activation analysis and waste classification. Especially, the cobalt, which transforms to 60Co, plays an important role. The 60Co, strong gamma emitter, affects the waste classification, safety analysis of decommissioning workers, and determination of segmentation and package plans. In this paper, effects of impurity concentration on activation analysis is studied. The expected impurity from various sources, including NUREG/CR-3474, commercial NPP data, etc, and effects will be demonstrated. Also, the comparison between results and international experiences will be followed.

HIC refers to a radwaste packaging container that can maintain integrity for more than 300 years in the general underground environment and disposal conditions in Korea. For HIC, the integrity of containers is verified according to the HIC regulation guideline for LLW and ILW disposal. Existing material tests include mechanical stability, permeability resistance, corrosion properties, chemical durability and biological resistance. In this study, a chemical durability test was conducted to prove the suitability of the HIC material by measuring the degree of chemical influence other than corrosion from the disposal environment. The chemical resistance evaluation method was used to simulate the disposal environment in the underground repository, and the amount of change in the physical properties of the degraded polymer concrete specimens according to the test time was confirmed. The technical standards considered leaching of material components, sulfation attack, acid attack, alkali, carbonate, and salt crystallization. The compressive strength and weight change of the specimens with time were checked by immersing them in a chemical solution that could leak major hazardous substances and wastes in the groundwater of the repository for several months. In addition, in order to evaluate the integrity in condition severe than the disposal environment, a flow was applied to a chemical solution having a concentration twice that of the basic chemical resistance test conditions, and the test period was extended twice to accelerate the deterioration of the specimen.

The Korea Nuclear Safety Act defines a high integrity container (HIC) as “a radioactive waste packaging container that can maintain its integrity for more than 300 years under the general underground environment and disposal conditions in Korea”, and detailed technical standards are not described. The US Nuclear Safety Commission’s “Low-Level Waste Licensing Branch Technical Position on Waste Form” describes the detailed requirements for solidification and HIC. The main contents of the US NRC technical position include limiting the free standing water, minimum design life, demonstrating mechanical, thermal and radiation stability, etc. In this study, the stability evaluation was performed to understand the mechanical strength with respect to horizontal and vertical loads. The basic property of polymer concrete was carefully evaluated, including compressive strength, structural fatigue resistance, etc. The long term creep test, loading of 40% of compressive strength, indicates that the polymer concrete exhibits good long term mechanical integrity.

After the Fukushima accident in 2011, a huge amount of radioactively contaminated water is being generated by cooling the melted fuel of units 1, 2 and 3. Most of contaminated water is seawater and underwater containing not only salt elements but also nuclear fission products with radioactivity. To treat the contaminated water, Cs/Sr removal facilities such as KURION and SARRY are being operated by TEPCO. Additionally, three ALPS facilities are on operation to meet the regularity standards for discharge to the sea. However, massive secondary wastes such as Zeolite, sludge and adsorbent is being generated by these facilities for liquid water treatment. The secondary wastes containing various radionuclide with Cs and Sr is difficult to store due to highly radioactive concentration and corrosive properties. In Japan, a variety of technologies such as GeoMelt vitrification, In-Can vitrification and CCIM vitrification is considered as a promising solution. In this study, they were reviewed, and the advantage and disadvantage of each technology were evaluated as the candidate technologies for thermal treatment of sludge radwaste.