This study is about the optical properties of InP-based quantum dot nanoparticles depending on their core/shell structure. The need to synthesize non-cadmium-based quantum dot nanoparticles with high quantum efficiency has become necessary due to the harmful effects of the element cadmium. We synthesized three types of quantum dot nanoparticles in 2000ml three-necked flasks by varying the synthesis temperature and time to have the same PL spectra according to the composition of the core and shell. The PL spectra, absolute quantum efficiency, and nanoparticle size were compared and analyzed according to the composition at red emission wavelengths of 614, 616, and 630 nm. InP/ZnSe/ZnS nanoparticles were synthesized with the highest PL-AQY of 94% at 614 μm, and Ga-doped InP/GaP/ZnSe/ZnS nanoparticles were synthesized with the highest PL-AQY of 97% at 616 μm. InZnP/ZnSe/ZnS nanoparticles with alloy cores were able to synthesize quantum dot nanoparticles with a peak PL-AQY of 98% at 630μm.

In this study, a mixed resin containing Bis-GMA was developed to produce a light-emitting sign using quantum dots. As a result of measuring the viscosity, color coordinates change, and luminance of the mixed resin, the following conclusions were obtained. The viscosity of the mixed resin decreased as the content of the diluent increased, and viscosity values ​​ranged from 3,627 to 1,349cps showed as a result. The viscosity of the mixed resin decreased as the temperature increased, and the viscosity showed a value of 5,156 to 1,132cps. For the optical properties of InP/GaP/ZnSe/ZnS quantum dots, the absolute quantum efficiency was 91% at 522nm and 90% at 618nm when the gallium was 0.01%. The luminance of the light-emitting sign using the resin mixed with quantum dots was showed 142.6cd/m2 in white and 104.2cd/m2 in the red region.

A drop weight impact test was conducted in this study to analyze the mechanical and thermal properties caused by the changes in the ratio of carbon fiber reinforced plastic (CFRP) to ethylene vinyl acetate (EVA) laminations. The ratios of CFRP to EVA were changed from 10:0 (pure CFRP) to 9:1, 8:2, 6:4, and 5:5 by manufacturing five different types of samples, and at the same time, the mechanical/thermal properties were analyzed with thermo-graphic images. As the ratio of the CFRP lamination was increased, in which the energy absorbance is dispersed by the fibers, it was more likely for the brittle failure mode to occur. In the cases of Type 3 through Type 5, in which the role of the EVA sheet is more prominent because it absorbs the impact energy rather than dispersing it, a clear form of puncture failure mode was observed. Based on the above results, it was found that all the observation values decreased as the EVA lamination increased compared with the CFRP lamination. The EVA lamination was thus found to have a very important role in reducing the impact. However, the strain and temperature were inversely propositional.

Rapid industrial development in recent times has increased the demand for light-weight materials with high strength and structural integrity. In this context, carbon fiber-reinforced plastic (CFRP) composite materials are being extensively used. However, laminated CFRPs develop faults during impact because CFRPs are composed of mixed carbon fiber and epoxy. Moreover, their fracturing behavior is very complicated and difficult to interpret. In this paper, the effect of the direction of lamination in CFRP on the absorbed impact energy and impact strength were evaluated, including symmetric ply (0°/0°, –15°/+15°, –30°/+30°, –45°/+45°, and –90°/+90°) and asymmetric ply (0°/15°, 0°/30°, 0°/45°, and 0°/90°), through drop-weight impact tests. Further, the thermal properties of the specimens were measured using an infrared camera. Correlations between the absorbed impact energy, impact strength, and thermal properties as determined by the drop-weight impact tests were analyzed. These analyses revealed that the absorbed impact energy of the specimens with asymmetric laminated angles was greater than that of the specimens with symmetric laminated angles. In addition, the asymmetry ply absorbed more impact energy than the symmetric ply. Finally, the absorbed impact energy was inversely proportional to the thermal characteristics of the specimens.