This study aimed to develop an efficient recycling process for wastewater generated from soil-washing used to remediate uranium (U(VI))-contaminated soil. Under acidic conditions, U(VI) ions leached from the soil were precipitated and separated through neutralization using hydrazine (N2H4). N2H4, employed as a pH adjuster, was decomposed into nitrogen gas (N2), water (H2O), and hydrogen ions (H+) by hydrogen peroxide (H2O2). The residual N2H4 was precipitated when the pH was adjusted using sulfuric acid (H2SO4) to recycle the wastewater in the soil-washing process. This purified wastewater was reused in the soil-washing process for a total of ten cycles. The results confirmed that the soil-washing performance for U(VI)-contaminated soil was maintained when using recycled wastewater. All in all, this study proposes an efficient recycling process for wastewater generated during the remediation of U(VI)-contaminated soil.

The nuclear facilities at Korea Atomic Energy Research Institute (KAERI) have generated a variety of organic liquid radwaste and radiation levels are also varied. At KAERI, the organic liquid radwaste has been stored at Radioactive Waste Treatment Facility (RWTF) temporarily due to the absence of the recognized treatment technique while inorganic liquid radwaste can be treated by evaporation, bituminization, and solar evaporation process. The organic liquid radioactive waste such as spent oil, cutting oil, acetone, ethanol, etc. was generated from the nuclear facilities at KAERI. Among the organic liquid radioactive wastes, spent oil is particularly significant. According to the nuclear safety act, radioactive waste can be cleared by incineration and landfilling if it meets the criteria of less than 10 μSv/h for individual dose and 1 person – Sv/y for collective dose. Dose assessment was performed on some organic liquid radioactive waste with a very low possibility of radioactive contamination stored in RWTF at KAERI. As a result, it was confirmed that some wastes met the regulatory clearance standards. Based on this, it was approved by the regulatory body, and this became the first case in Korea and KAERI for permission for regulatory clearance of organic liquid radioactive waste by landfill after incineration.

Spent ion exchange resins have been generated during the operation of nuclear facilities. These resins include radioactive nuclides. It is needed to fabricate them into a stable form for final disposal. Cement solidification process is a useful method for the fabrication of them into a waste form for final disposal. In this study, proper conditions for the fabrication of them into a stable waste form were determined using the cement solidification process. In-drum waste forms were then produced at the conditions, where the stability of representative samples was evaluated for final disposal. The samples were satisfied to the Waste Acceptance Criteria for low and intermediate level radioactive waste disposal sites. This result can be utilized to derive optimal conditions for the fabrication of spent ion exchange resins into a final disposal form.

There is a large amount of radioactive waste in waste storage in the Korea Atomic Energy Research Institute. Some of the radioactive waste was generated during the dismantling process due to Korea Research Reactor 1&2 and it accounts for 20% of the total waste. Radioactive waste must be reduced by appropriate disposal methods to secure storage space and to reduce disposal costs. Research Reactor wastes include wastes that are below the acceptable criteria for selfdisposal and non-contaminated wastes, so they can be treated as wastes subject to self-disposal through contamination analysis and reclassification. In order to deregulation radioactive waste, it is necessary to meet the self-disposal standards stipulated in the Domestic Nuclear Act and the treatment standards of the Waste Management Act. The main factors of deregulation are surface contaminant, radionuclide activity and dose assessment. To confirm the contamination of waste, surface contaminant and gamma nuclide analysis were performed. After homogenizing the waste sample, it was placed in 1 L Mariinelli beaker. When collecting waste samples, 1 kg per 200 kg of waste was collected. The concentrations of the major radionuclides Co-60, Cs-134, Cs-137, Eu-152, and Eu-154 were analyzed using HPGe detector. To evaluate radiation dose, various computational programs were used. A dose assessment was performed with the analyzed nuclide concentration. The concentrations of representative nuclides satisfied the deregulation acceptance criteria and the results of the dose assessment corresponding to self-disposal method was also satisfied. Based on this results, KAERI submitted the report on waste self-disposal plan to obtain approval. After final approval, Research Reactor waste is to be incinerated and incineration ash is to be buried in the designated place. Some metallic waste has been recycled. In this study, the suitability of deregulation for self-disposal was confirmed through the evaluation of the surface contaminant analysis, radionuclide concentration analysis and dose assessment.

Natural uranium-contaminated soil in Korea Atomic Energy Research Institute (KAERI) was generated by decommissioning of the natural uranium conversion facility in 2010. Some of the contaminated soil was expected to be clearance level, however the disposal cost burden is increasing because it is not classified in advance. In this study, pre-classification method is presented according to the ratio of naturally occurring radioactive material (NORM) and contaminated uranium in the soil. To verify the validity of the method, the verification of the uranium radioactivity concentration estimation method through γ-ray analysis results corrected by self-absorption using MCNP6.2, and the validity of the pre-classification method according to the net peak area ratio were evaluated. Estimating concentration for 238U and 235U with γ-ray analysis using HPGe (GC3018) and MCNP6.2 was verified by 􀟙-spectrometry. The analysis results of different methods were within the deviation range. Clearance screening factors (CSFs) were derived through MCNP6.2, and net peak area ratio were calculated at 295.21 keV, 351.92 keV(214Pb), 609.31 keV, 1120.28 keV, 1764.49 keV(214Bi) of to the 92.59 keV. CSFs for contaminated soil and natural soil were compared with U/Pb ratio. CSFs and radioactivity concentrations were measured, and the deviation from the 60 minute measurement results was compared in natural soil. Pre-classification is possible using by CSFs measured for more than 5 minutes to the average concentration of 214Pb or 214Bi in contaminated soil. In this study, the pre-classification method of clearance determination in contaminated soil was evaluated, and it was relatively accurate in a shorter measurement time than the method using the concentrations. This method is expected to be used as a simple pre-classification method through additional research.

It is important to make a strategy for clearance-level radioactive waste. Sampling and disposal plans should be drawn up with characteristics of target waste. In this paper, a target clearance-level radioactive waste is used in a laboratory for experiments with Cs-137 and Co-60, unsealed radioactive sources with gamma radiation isotopes. Therefore, it is enough to analyze with HPGe to check the contaminant level. The laboratory fume hood combined multiple materials, which means some are volume contamination and others are surface contamination. The wood, plastic, and drywall boards, which are absorbent volume contaminated parts and make up PVC pipes, base cabinet doors, backside baffles, etc., will be sampled with coring methods. The metals and glasses, which are unabsorbent, surface-contaminated parts, are sampled with smear methods. The work surface, baffles, exhaust plenum, and glass sash inside parts have a high possibility of being contaminated. The hood body, flame, base cabinet, PVC pipe (the rare end of the filter), and blower transition case have a low possibility of becoming contaminated. When we checked with HPGe, except for the work surface (which was below clearance level), other parts were less than MDA. The highest radionuclide concentration was in PVC pipe: Cs-137C 3.91E-02 (Bq/g), Co-60 4.54E- 03 (Bq/g). It is less than clearance level. Therefore, the waste was applied for the clearance level radioactive wastes and got permission from the regulatory body.

The nuclear facilities at Korea Atomic Energy Research Institute (KAERI) have generated a variety of liquid radioactive waste and most of them have low-level radioactive or lower levels. Some of the liquid radioactive waste generated in KAERI is transported to Radioactive Waste Treatment Facility (RWTF) in 20 L container. Liquid radioactive waste transported in a 20 L container is stored in a Sewer Tank after passing through a solid-liquid separation filter. It is then transferred to a very low-level liquid radioactive waste Tank after removing impurities such as sludge through a pre-treatment device. The previous pre-treatment process involved an underwater pump and a cartridge filter device passively, but this presented challenges such as the inconvenience of having to install the underwater pump each time, radiation exposure for workers due to frequent replacement of the cartridge filter, and the generation of large amounts of radioactive waste from the filter. To address these challenges and improve efficiency and safety in radiation work, an automated liquid radioactive waste pre-treatment device was developed. The automated liquid radioactive waste pre-treatment device is a pressure filtration system that utilizes multiple overlapping filter plates and pump pressure to effectively remove impurities such as sludge from liquid radioactive waste. With just the push of a button, the device automatically supplies and processes the waste, reducing radiation hazards and ensuring worker safety. Its modular and mobile design allows for flexible utilization in various locations, enabling efficient pre-treatment of liquid radioactive waste. To evaluate the performance of the newly constructed automated liquid radioactive waste treatment device, samples were taken before and after treatment for 1 hour cycling and analyzed for turbidity. The results showed that the turbidity after treatment was more than about four times lower than before treatment, confirming the excellent performance of the device. Also, it is expected that the treatment efficiency will improve further as the treatment time and number of cycles increase.

In general, dose assessment must be performed to obtain approval for clearance of radioactive waste. If the annual dose criteria through dose evaluation satisfies the clearance condition, radioactive waste can be disposed of. Various programs are used to perform dose assessment. NRCDOSE GASPAR is used as a program to assess the amount of radiation exposed to atmospheric emissions. Program is easy to use and results can be checked immediately after execution. GASPAR requires main input factors by exposure route such as site specifics, source term, special location, block data. Basically, program has default input values but user can easily modify it. The most important factor is that when entering a nuclide, the effect on progeny radionuclides is not automatically calculated. User should consider the dose contribution from progeny radionuclides. In this study, dose assessment was performed for combustible waste incineration using NRCDOSE GASPAR. And it was confirmed that exposure dose of individuals and groups criteria for clearance regulation.

In KAERI, Waste storage facility in the radiation management area has stored a large amount of wood waste. The amount of waste is approximately 27,000 kg, it accounts for 17% of the total waste in waste storage facility. Proper disposal of wood waste improves the fire resistance performance, secure storage space and reduce disposal costs. In order to self-disposal of wood waste, it is necessary to satisfy the self-disposal standards stipulated by the domestic Atomic Energy Act and the treatment standards of the Waste Management Act. The main factors of standards are surface contaminant, radionuclide activity and radiation dose effects. To confirm the contamination of wood waste, direct indirect measurement methods and gamma nuclide analysis were performed. To evaluate radiation dose, various computational programs were used. The results of the analysis were satisfied with domestic regulations on the classification and self-disposal of radioactive wastes. Based on this results, KAERI submitted the report on wood waste self-disposal plan to obtain approval. After final approval, wood waste is to be incinerated and incineration ash is to be buried in the designated place. The objective of this study is to provide total procedure of wood waste self-disposal and effective representative sampling method.

There are various types of level gauging method such as using float, differential pressure, hypersonic, displacement and so on. In this study, among them, the method utilizing the differential pressure was reviewed. The strengths include: the differential pressure type level gauge can measure the level without direct contact of the sensor with media. That is to say, the level can be measured even if the sensor is far away from the tank. And regardless of the size of the tank, the level can be measured if the pneumatic pipes are installed. The weaknesses include: the sensor needs intermedium to recognize the level. The intermedium utilizes a fluid, which is compressed air. It is difficult to handle that compressed air has the properties of a gas. And to make compressed air needs compressor, tank and pneumatic pipes. So if you have many tanks, you need to install exponentially the pneumatic pipes. As well, level measurement range is limited to the points where the pneumatic pipes of the tank is installed. And if a compressed air that supplies to the sensor leaks, uncertainty will increase. A compressed air is colorless and odorless, so it’s difficult to pinpoint the leak. Finally, events like cracks and clogging can cause inaccurate measurement. Rather than using only differential pressure, it is better to use another measurement method according to the situation of the facility.

Strong acidic wastewater containing a radionuclide is generated from the decontamination of radioactively contaminated wastes or equipment. This wastewater is generally treated though a precipitation process using an alkali (alkali earth) hydroxides. In this precipitation process, a significant amount of alkali (alkali earth) sulfates are generated, which is the reason for the increase in the radioactive waste generation. In this study, a method for separating only radionuclides and metal ions from the wastewater was evaluated. For this reason, precipitation behaviors of radionuclides and metal ions by hydrazine injections were investigated using equilibrium calculations. In addition, behaviors of hydrazine decomposition after removal of radionuclides and metal ions were analyzed for recycling the wastewater.

Following a radioactive waste criterion and clearance level radioactive waste Act Article 2. “The radioactive wastes confirmed by the Commission as having concentration by nuclide not exceeding the value determined by the Commission through incineration, reclamation, recycling, etc”. The combustible clearance level radioactive wastes like lumbers are incinerated and non-combustible wastes like concreted are buried. The metals clearance level radioactive wastes are recycled after being re-molded. However, the clearance level radioactive waste with keeping its original forms is not common. Due to the nature of KAERI, the equipment are brought into the radiation-controlled zone for experiments. Those equipment are conservatively considered contaminated and categorized with radioactive waste following nuclear safety acts. In this case, the spectroscopy device which is clearance level radioactive waste is self-disposed for use in non-controlled areas. The 4 devices are composed of 3 gamma-ray spectroscopy and 1 alpha, beta counting system. Those devices were used for clearance level radioactive waste’s radioisotope analysis in Radioactive Waste Form Test Facility which is used in a separated room for analysis. This room will be released in nonradiation controlled area, therefore those devices will be moved to non-controlled area and keep using. Last April self-disposal was reported to the regulatory body and got acceptance last May. Those devices were moved to non-controlled area last July. This case will be good example for reuse equipment which stop using in radiation controlled area but can keep used.

The radwaste facility management team is preparing for clearance of 4 MCAs in The Radwaste Form Test Facility (RFTF). The targeted waste was used for clearance level radioactive waste sample analysis and has been used for this purpose since the early 2000s. Due to the characteristics of clearance level radioactive waste, the concentration of radioactivity is very low and MCA is used with Marinelli beakers the possibility of contamination is low. Moreover, the radiation detector should not be contaminated with radioactive materials, it should be less than the clearance level. These detectors were considered surface contamination materials. To detect the contaminated spot of each material, we scanned the whole surface of a material with a gamma survey meter. After that, we took a sample from 1×1 m2 and a total of 30 samples from each MCA. The wiped filter paper was analyzed with alpha, beta low background counting systems. The results of the analysis of the smear sample of total alpha and beta nuclide radioactivity were less than MDA (α: 2.88×10−5 Bq·cm−2, β: 3.07×10−5 Bq·cm−2). The major nuclide in this facility is Co-60 and Cs-137 therefore we analyzed gamma nuclide activity with HPGe. The maximum specific activity was Co-60: 2.31×10−5 Bq·cm−2, Cs-137: 1.96×10−6 Bq·cm−2. If it is satisfied with the clearance criteria, detectors will be reused at the Radioactive Waste Treatment Facility (RWTF) room # 7251 uncontrolled area.

According to the Atomic Energy Act of Korea, radioactive waste can be cleared when it meets the criteria, less than 10 uSv·y−1 for individual dose and 1 person · Sv·y−1 for collective dose. Consequently, it is necessary to evaluate radiation dose to get permission for regulatory clearance from the regulatory body of Korea. Several computational programs can be used for dose calculation depending on disposal methods such as landfill, incineration, and recycling. As for incineration, the effects of radionuclide emitted during combusting radwaste have to be considered to figure out exposure dose. In this study, GASPAR code is described to assess exposure dose from effluents released to the atmosphere during incinerating combustible radioactive wastes for regulatory clearance. GASPAR is the code programmed by Radiation Safety Information Computational Center at Oak Ridge National Laboratory for computing annual dose due to radioactive effluents released from a nuclear power plant to the atmosphere during routine operation. The calculating methods of the code are based on the mathematical model of U.S. NRC regulatory guide 1.109, about beta and gamma radiation from noble gas in semi-infinite plume, radioiodine, and particulates. GASPAR evaluates both individual dose and population dose. The considering pathways are composed of external exposure by plume and ground deposition of effluents, and internal exposure as a result of inhalation and food ingestion. Since the calculation model of GASPAR requires various variables about the radionuclide and disposal site, the accuracy of the results is decided by inputted values. The program contains the default values to parameters such as the humidity, fraction of deposition, and storage time of foods. However, to get permission, it is important to use the appropriate data representing the condition of the combustion scenario as substitutes for the default since the values are localized to the country where the code was developed. Therefore, dose assessment by GASPAR code can be applied for regulatory clearance by incineration, when reliable values depending on the disposal plan inputted.

Li-Cd 합금을 이용한 환원추출방식을 LiCl-KCl 기반의 drawdown 공정에 적용하게 되면, LiCl-KCl 공융염의 조성이 파괴되므로 공정온도를 높여야 하며, 전해정련 및 전해제련과 같은 공정에 LiCl-KCl 용융염을 재사용할 수 없게 된다. 따라서, 본 연구에서는 공융염 조성에 적합한 Li-K-Cd 합금을 제조하였으며, 이를 이용하여 U와 Nd가 포함된 LiCl-KCl 염에 투입하여 용 융염 내 UCl3의 제거가 가능한지 평가하였다.