The amount of waste water generated from the domestic sources is consistently increasing in proportion to economic growth, and the conventional activated sludge process is widely being used for general waste water treatment. But the ministry of environment becomes stringthent treatment standards of N and P (less than 20mg/L of N, 2mg/L of P) to prevent the eutrophication of lake water, and therefore highly advanced treatment technology is required not only in the existing treatment plants where the activated sludge process is being used, but also in newly constructed treatment plants for the treatment of N and P. This study is aimed at highly operating the engineering technology method was developed by domestic to eliminate N and P at the same time. Experiments were conducted in the treatment plant located in Yong In city. The bioreactor was started from the principal equipment for the elimination of N and P and the elimination of organic compounds. It consists of an internal recycle piping from the end of the aerobic tank to the anoxic tank and external recycle piping from the final settling basin to the denitrification tank. By experiment of 4 types separate inflow of waste water to the denitrification tank and the anaerobic tank, and changes in staying time at the anoxic tank and the aerobic tank, the elimination of organic compounds in each type and the relationship in the efficiency between the elimination of N and P were researched.

Caustic (NaOH) solution is used to remove H2S from hydrocarbon streams in petroleum refining industry, gradually being, so called, spent sulfidic caustic (SSC) which has high levels of H2S and alkalinity. Thus, SSC can be used as an electron donor and a buffering agent for autotrophic denitrification. As SSC, however, contains some non-biodegradable organics, air stripping was conducted to remove the non-biodegradable organics. As a result, over 93 % of the non-biodegradable organics was removed within 30 min of aeration. Then, Na2S2O3·5H2O, methanol and organic matters, which are produced from a biodiesel production plant, were added to reform the air-stripped SSC and their products being referred to new sulfidic caustics (NSCs)Ⅰ, Ⅱ and Ⅲ, respectively. Thereafter, to investigate the effect of these products on the removal of COD and TN, these products were injected to a biological nitrogen removal (BNR) process, resulting in additional 44 % TN removal without noticeable increase in the effluent COD level. Therefore, it can be said that the BNR process is a promising option to treat NSC as demonstrated in this study whose results can be useful for developing resource recovery technologies.