Super P (SP) is a conductive carbon black that significantly enhances the electrical conductivity of various types of electrodes, making it a widely preferred conductive agent in lithium-ion batteries. By contrast, activated carbon (AC), originally used in capacitors due to its porous structure, is expected to contribute to electrochemical performance through its enhanced interaction with lithium ions. First, the physical properties of both materials were analyzed through various characterization techniques such as scanning electron microscopy (SEM), X-ray diffraction (XRD), and transmission electron microscopy (TEM) to confirm the increase in electrochemical properties through the combination of SP and AC. Furthermore, the microstructure and electrical properties of the LiFePO4 (LFP) electrode were analyzed, to determine the impact on battery performance. With a 1.15 M LiPF6 in an ethylene carbonate/diethyl carbonate (EC/DEC) electrolyte, the results indicated that SP-only electrodes exhibited the highest conductivity and lowest surface resistance, making them the most effective at maintaining stable electrochemical performance. In contrast, electrodes with only AC showed higher resistance, demonstrating that SP remains superior in improving LFP electrode conductivity, ultimately optimizing lithium-ion battery performance.
The raw material selected for this research was Brazil chestnut shells (BCs), which were utilized to gain porous carbon as a positive electrode for lithium–sulfur batteries (LSBs). The effects of N/S co-doped on the electrochemical properties of porous carbon materials were studied using thiourea as nitrogen and sulfur sources. The experimental results indicate that the N/S co-doped carbon materials have a higher mesopore ratio than the undoped porous carbon materials. The porous carbon material NSPC-2 has a lotus-like structure with uniform pore distribution. The N and S doping contents are 2.5% and 5.4%. The prepared N/S co-doped porous carbon materials were combined with S, respectively, and three kinds of sulfur carbon composites were obtained. Among them, the composite NSPC-2/S can achieve the initial specific discharge capacity of 1018.6 mAh g− 1 at 0.2 C rate. At 1 C rate, the initial discharge capacity of the material is 730.6 mAh g− 1, and the coulomb efficiency is 98.6% and the capacity retention rate is 71.5% after 400 charge–discharge cycles.
In this work, subabul wood biomass was used to prepare carbon adsorbents by physical and chemical activation methods at various carbonization temperatures. The properties of the carbon adsorbents were estimated through characterization techniques such as X-ray diffraction, Fourier transform infrared spectroscopy, X–ray photo electron spectroscopy, laser Raman spectroscopy, scanning electron microscopy, CHNS-elemental analysis and N2 adsorption studies. Subabul-derived carbon adsorbents were used for CO2 capture in the temperature range of 25–70 °C. A detailed adsorption kinetic study was also carried out. The characterization results indicated that these carbons contain high surface area with microporosity. Surface properties were depended on treatment method and carbonization temperature. Among the carbons, the carbon prepared after treatment of H3PO4 and carbonization at 800 °C exhibited high adsorption capacity of 4.52 m.mol/g at 25 °C. The reason for high adsorption capacity of the adsorbents was explained based on their physicochemical characteristics. The adsorbents showed easy desorption and recyclability up to ten cycle with consistent activity.
In today’s world, carbon-based materials research is much wider wherein, it requires a lot of processing techniques to manufacture or synthesize. Moreover, the processing methods through which the carbon-based materials are derived from synthetic sources are of high cost. Processing of such hierarchical porous carbon materials (PCMs) was slightly complex and only very few methods render carbon nano-materials (CNMs) with high specific surface area. Once it is processed, which paves a path to versatile applications. CNMs derived from biological sources are widespread and their application spectrum is also very wide. This review focuses on biomass-derived CNMs from various plant sources for its versatile applications. The major thrust areas of energy storage include batteries, super-capacitors, and fuel cells which are described in this article. Meanwhile, the challenges faced during the processing of biomass-derived CNMs and their future prospects are also discussed comprehensively.
High-performance carbon materials were prepared via a one-step molten salt carbonization of tobacco waste used as electrode materials for supercapacitors. Carbon material prepared by carbonization for 3 h in molten CaCl2 at 850 °C exhibits hierarchically porous structure and ideal capacitive behavior. In a three-electrode configuration with 1 mol L− 1 H2SO4 aqueous solution, it delivers specific capacitance of 196.5 F g− 1 at 0.2 A g− 1, energy density of 27.2 Wh kg− 1 at 0.2 A g− 1, power density of 983.5 W kg− 1 at 2 A g− 1, and excellent cyclic stability with 94% capacitance retention after 5000 charge–discharge cycles at 1 A g− 1. Moreover, in a symmetrical two-electrode configuration with 6 mol L− 1 KOH aqueous solution, it delivers specific capacitance of 111.1 F g− 1 at 0.2 A g− 1, energy density of 3.8 Wh kg− 1 at 0.2 A g− 1, and power density of 482.0 W kg− 1 at 2 A g− 1. The relationship between hierarchically porous structure and capacitive performance is also discussed.
Cost-effective and sustainable high-performance supercapacitor material was successfully prepared from cellulosic waste (Sapindus trifoliatus nut shells) biomass-derived activated carbon (CBAC) by physical activation method. The CBAC displays nanofiber morphology, high specific surface area (786 m2/ g), large pore volume (0.212 cm3 g− 1) which are evaluated using FESEM, BET and possessed excellent electrochemical behavior analyzed through various electrochemical methods. Moreover, the assembled symmetric CBAC//CBAC device exhibits high specific capacitance of 240.8 F g− 1 with current density of 0.2 A g− 1 and it is maintained to 65.6 F g− 1 at high current density of 2.0 A g− 1. In addition, the symmetric device delivers an excellent specific energy maximum of over 30 Wh kg− 1 at 400 W kg− 1 of specific power and excellent cycling stability in long term over 5000 cycles. The operation of the device was tested by light-emitting diode. Hence, CBAC-based materials pave way for developing large-scale, low-cost materials for energy storage device applications.
To meet the increased performance and cost requirements of commercial supercapacitor, a N and O self-doped hierarchical porous carbon is fabricated via a green and simple self-activation route utilizing leaves of wild hollyhock as raw materials. Comparing to commercial activated carbon, the reported material exhibits some marked merits, such as simple and green fabrication process, low cost, and superior capacitance performance. The specific surface area of the obtained N and O codoped hierarchical porous carbon arrives 954 m2 g−1, and the content of the self-doped nitrogen and oxygen reaches 2.64 at.% and 7.38 at.%, respectively. The specific capacitance of the obtained material reaches 226 F g− 1 while the specific capacitance of the symmetric supercapacitor arrives 47.3 F g− 1. Meanwhile, more than 90.3% of initial specific capacitance is kept under a current density of 20 A g− 1, and no arresting degradation is observed for capacitance after 5000 times cycle, perfectly demonstrating the excellent cycle and rate capability of the obtained material. The obtained N and O co-doped hierarchical porous carbon are expected to be an ideal substitution for commercial activated carbon.