PURPOSES : Snow-removal performance is performed in this study to assess the feasibility of replacing calcium-chloride solution with sodium chloride solution at the minimum temperature of -5 ℃ during snowfall. METHODS : The atmospheric temperature distribution in Seoul was analyzed. The manufacturing, storage, and indoor melting performance of calcium-chloride and sodium-chloride solutions were evaluated, and on-site snow-removal performance was evaluated based on the solution type. RESULTS : According to the results of the melting performance test at -5°C, the melting capacity of the sodium chloride solution was expressed at a level exceeding 90% of that of the calcium chloride solution, indicating a similar melting performance between the two solutions. Additionally, based on the snow removal performance test using aqueous solutions, the snow removal performance of the sodium chloride solution was found to be approximately 96% compared to that of the calcium chloride solution, indicating minimal differences in snow removal performance due to changes in the type of solution. CONCLUSIONS : Similar snow-removal performance was achieved when the sodium chloride solution was used instead of calciumchloride aqueous solution at temperatures exceeding -5 ℃.

본 연구는 도로시설물의 염화칼슘 제거를 위한 미세기포 세척장비의 최적 운용조건에 대하여 성능평가를 수행하였다. 실험에 사용된 미세기포의 직경은 196.6±100.6nm 에 1.36×108개/ml의 농도를 나타낸다. 세척장비의 분사장치에 대한 실험 성능결과, 100bar의 분사압력에서 100cm, 150cm 분사거리에 약 93%, 91%의 세척효율이 나타나는 것으로 확인되었다. 미세기포 생성(순환)횟수를 2-6회로 증가시킴에 따라 최소 1%에서 7%까지 염화물 제거율이 높아짐을 확인하였다. 미세기포 생성 공기유량을 4 ml/min에서 0.5 ml/min으로 낮춤에 따라 세척효율이 최대 30%까지 증가하는 것이 확인되었다. 일반 상수도와 미세기포의 세척효율은 미세기포가 일반상수도 보다 세척효율이 25% 높게 나타났다.

In this work, a nickel metal (Ni) electroplating on the activated carbon fiber (Ni/ACFs) surfaces was carried out to remove the toxic hydrogen chloride (HCl) gas. The surface properties of the treated ACFs were determined by using nitrogen adsorption isotherms at 77 K, SEM, and X-ray diffraction (XRD) measurements. HCl removal efficiency was confirmed by a gas-detecting tube technique. As a result, the nickel metal contents on the ACF surfaces were increased with increasing the plating time. And, it was found that the specific surface area or the micropore volume of the ACFs studied was slightly decreased as increasing the plating time. Whereas, it was revealed that the HCl removal efficiency containing nickel metal showed higher efficiency values than that of untreated ACFs. These results indicated that the presence of nickel metal on the ACF surfaces played an important role in improving the HCl removal over the Ni/ACFs, due to the catalytic reactions between nickel and chlorine.

The atmospheric pressure plasma treatments (Ar/O2 and Ar/N2) of activated carbon fibers (ACFs) were carried out to introduce hydrophilic functional groups on carbon surfaces in order to enhance the hydrogen chloride gas (HCl) adsorption. Surface properties of the ACFs were determined by XPS and SEM. N2/77 K adsorption isotherms were investigated by BET and D-R (Dubinin-Radushkevich) plot methods. The HCl removal efficiency was confirmed by HCl detecting tubes (range:1~40 or 40~1000 ppm). As experimental results, it was found that all plasma-treated ACFs showed the decrease in the pore volume, but the HCl removal efficiency showed higher level than that of the untreated ACFs. This result indicated that the plasma treatments led to the conformation of hydrophilic functional groups on the carbon surfaces, resulting in the increase of the interaction between the ACFs and HCl gas.

The aim in this study was to remove Cl−, which can be problematic in the recycling of bottom ash, by identifying the optimum operating conditions for a soil electrolysis apparatus with spiral paddles and to use these as the base data in removing contaminants from various polluted soils using electrolysis. Unprocessed bottom ash collected from the openair storage yard at thermoelectric power plant H in Gyeong sang nam - do Province was used as the experimental material. The experimental methodology was to identify the optimum operating conditions to remove Cl− contained in the bottom ash using the following variables: use or not of spiral paddles, application or not of electrolysis, change of concentration of the electrolyte solution, electrolysis application time, and the voltage level during electrolysis. From the results, the highest removal efficiency of 91.4% was shown under the following conditions: use of the spiral paddles, use of 0.3% NaOH electrolyte solution, 20 min of electrolysis; and a voltage level of 5 V during electrolysis. It is evident that application of the soil electrolysis apparatus for removal of Cl− from bottom ash could be valuableas base data for purification of polluted soils in the future.

Recently, self-healing concrete has been researched as maintenance and repair of concrete structures are important challenges we face. This paper focused on possibility of ion exchange resin as a novelty material directly and actively controlling harmful ions of concrete, whereas most self-healing concrete researches have been focused on methods to automatically filling and repairing internal crack of concrete. Because equilibrium properties between ion exchange resin and harmful ion is important before design of cement mixing proportion, it was conducted to remove chloride or sulfate in saturated Ca(OH)2 solutions containing NaCl or Na2SO4. The removal performance was analyzed using kinetic equation and isothermal equation. Consequently, the removal properties of anion exchange resin were relatively more dependent on pseudo second reaction equation and Langmuir equation than pseudo first reaction equation and Freundlich equation. And it was concluded that each chloride and sulfate can be removed to the maximum 1068 ppm and 1314 ppm.

The solid phase extractant (PVC-D2EHPA bead) was prepared by immobilizing di-2-ethylhexyl-phosphoric acid (D2EHPA) with polyvinyl chloride (PVC). The prepared PVC-D2EHPA beads were characterized by using fourier transform infrared spectrometer (FTIR) and scanning electron microscopy (SEM). The removal experiments of Cu(II) by PVC-D2EHPA beads conducted batchwise. The removal kinetics of Cu(II) was found to follow the pseudo-second-order model. The equilibrium data fitted well with Langmuir isotherm model and the maximum removal capacity was 2.6 mg/g at 20℃. The optimum pH region was in the range of 3.5 to 6. and the standard free energy (△Go) was between –4.67 ∼–4.98 kJ/mol, indicating the spontaneous nature of Cu(II) removal by PVC-D2EHPA beads.

The Raw water from Deer Creek (DC) reservoir and Little Cottonwood Creek (LCC) reservoir in the Utah, USA were collected for jar test experiments. This study examined the removal of arsenic and turbidity by means of coagulation and flocculation processes using of aluminum sulfate and ferric chloride as coagulants for 13 jar tests. The jar tests were performed to determine the optimal pH range, alum concentration, ferric chloride concentration and polymer concentration for arsenic and turbidity removal. The results showed that a comparison was made between alum and ferric chloride as coagulant. Removal efficiency of arsenic and turbidity for alum (16 mg/L) of up to 79.6% and 90.3% at pH 6.5 respectively were observed. Removal efficiency of arsenic and turbidity for ferric chloride (8 mg/L) of up to 59.5% at pH 8 and 90.6% at pH 8 respectively were observed. Optimum arsenic and turbidity removal for alum dosages were achieved with a 25 mg/L and 16 mg/L respectively. Optimum arsenic and turbidity removal for ferric chloride dosages were achieved with a 20 mg/Land 8 mg/L respectively. In terms of minimizing the arsenic and turbidity levels, the optimum pH ranges were 6.5 and 8for alum and ferric chloride respectively. When a dosage of 2 mg/L of potassium permanganate and 8 mg/L of ferric chloride were employed, potassium permanganate can improve arsenic removal, but not turbidity removal.