Environmental pollution has led to global warming, which threatens human life. In response, hydrogen is gaining attention as a next-generation energy source that does not emit carbon. Due to its explosive nature, special care must be taken in the safe storage and transportation of hydrogen. Among various storage methods, liquefied storage, which can reduce its volume to 1/800, is considered efficient. However, since its boiling point reaches -253°C, the design of an insulation system is essential. For the design of insulation systems applied to large containers, a membrane-type design is required, which necessitates the use of cryogenic adhesives. To evaluate whether the cryogenic adhesive is properly implemented, assessments such as tensile and shear tests are necessary. This study presents a methodology for shear evaluation. Conventional methods for shear evaluation of adhesives result in slippage, preventing proper assessment. Therefore, a method involving drilling holes in the gripper and pulling from the holes must be applied. Optimal design concerning the size and location of the holes is required, and this study derives optimal values based on finite element analysis. By conducting experiments based on the results of this study, it is expected that the risk of gripper damage will be minimized, allowing for accurate evaluation of the adhesive’s performance.
Conversion to modern hydrogen energy is required, and research on liquefied hydrogen cargo containment systems is needed for large-capacity transport and storage. In this study, changes in the mechanical properties of the adhesive required for storage and transport in liquid hydrogen were confirmed. The lap shear test was performed by realizing cryogenic conditions in a small chamber using liquid nitrogen and liquid helium. There was an increase of 11.0% in the -180℃ condition compared to room temperature, and an increase of 1.8% in the -230℃ condition compared to the -180℃ condition was confirmed. In the case of shear strain, it is known that it decreases as the temperature goes down. As a result of the experiment, it was confirmed that the value at room temperature and the value at -180℃ reduced the shear strain by 5.0%, and -230˚ compared to the -180℃ condition. An increase of 1.5% was confirmed in the C condition. In the case of the specimen tested at -230℃, the deformation in the gripper part was larger than in other tests, and it is judged that the maximum shear strength and shear strain were affected. In addition, in this study, there is a limitation in the experiment at -230°C rather than 253°C, which is the boiling point of hydrogen
In modern times, where problems due to environmental pollution are continuously occurring, hydrogen is in the spotlight as the energy of the future. Hydrogen is an eco-friendly energy resource that does not even generate CO2, and is actively supporting research to utilize hydrogen energy at the national level. This study is a study on the cryogenic mechanical properties of the elements constituting the cargo hold during the transportation of liquid hydrogen. Among the various components, the evaluation of mechanical properties of the cryogenic adhesive under liquid helium conditions was confirmed. The related contents are summarized as follows. As a result of performing SSRT by curing the adhesive, it was confirmed that tensile strength and maximum strain were increased at cryogenic temperature (-230°C) compared to room temperature (25°C). It was confirmed that the adhesive-hardened specimen showed a brittle fracture mode at both room temperature and cryogenic temperature during tensile. Improvements in this study, such as pores occurring during adhesive curing, the use of standard specimens, and experiments at -253°C, the boiling point of hydrogen, exist, and are planned to be carried out in subsequent studies.
Natural gas is the most realistic fuel among eco-friendly fuels. Natural gas production is limited, and in Korea, it is supplied and utilized in the form of liquefied natural gas (LNG). In the case of LNG, the vaporization point is 163 degrees below zero, so ordinary metal cannot be used due to its brittleness. The International Maritime Organization (IMO) defines metals that can be used in the IGC Code, and is used for storage containers, transportation containers, etc. based on the metals. Welding is essential in the manufacture of large structures such as LNG storage tanks. In this study, weldability studies related to cryogenic materials were conducted. In Part I of this study, high-manganese steel and part II were studied for two types of stainless steel (STS304L, STS316L), and in Part III, aluminum (AL5083). During laser welding, the shape of the Bead on Plate (BOP) was analyzed, and a total of nine cases were analyzed using laser power and welding speed as variables. It was confirmed that the penetration and the width of the welding width were linearly proportional to the amount of heat input. Based on this study, it is possible to conduct a follow-up study to find the optimal welding conditions for butt welding and fillet welding.
As the part of efforts to respond to the environmental pollution, the demand for clean energy is increasing. Natural gas is one of the most realistic alternatives, and interest in the storage and transportation containers to utilize the natural gas is growing. The production area of natural gas is limited, and in Korea, it is imported in the form of liquefied natural gas. LNG is a cryogenic state with a vaporization point of -163°C, so the ordinary metal cannot be used due to its brittleness. The international maritime organization (IMO) defines the metals that can handle LNG in the IGC Code, and the research is ongoing. This study was a preliminary study to check the weldability of related metals and confirmed the shape of bead on plate (BOP) during the laser welding for each material. In part I, a study was conducted on the high manganese steel, and in part II, a study was conducted on the materials of STS304L and STS316L among the stainless steel. Based on this study, it can be used as an optimal welding condition for the butt and fillet welding.
As demand for eco-friendly energy increases, demand for natural gas and Liquefied natural gas (LNG) storage technologies continues to increase. LNG is a cryogenic environment with a temperature of -163°C, so ordinary metals cannot be used due to brittleness. Accordingly, IGC Code designates the cryogenic materials such as Invar, STS304L, Al5083-0, and High Manganese Steel. For fabricating those materials, research on welding possibility is the most important. Thus this study focused on the possibility of laser welding of the cryogenic materials. The weldability of High Manganese Steel was researched in this paper, the shape and the dimensions of the beads after bead on plate (BOP) welding were observed. The experiment was conducted on a total of 25 cases with laser power and welding speed of 5 cases each, and the width, height, and penetration of the beads were confirmed. It was confirmed that the paramenter of bead increased linearly with the laser power, and the paramenters of bead increased linearly with decreasing welding speed. Based on this study, high manganese steel can be applied in various industries by applying it to butt welding.
Inconel 718 alloy has excellent mechanical properties at room temperature, high temperature and cryogenic conditions. UTS of base metal is about 900MPa at room temperature; this is increased up to 1300MPa after heat treatment & aging-hardening. Mechanical properties of Inconel 718 Alloy were similar to those shown in the the results for tensile test; mechanical properties of Inconel 718 alloy's GTAW were similar to those of base metal's properties at room temperature. Mechanical properties at cryogenic conditions were better than those at room temperature. Heat-treated Inconel 718, non- filler metal GTAW on Inconel 718 and GTAW used filler metal on Inconel 718's UTS was 1400MPa at cryogenic condition. As a result, the excellent mechanical properties of Inconel 718 alloy under cryogenic conditions was proved through tensile tests under cryogenic conditions. In addition, weldability of Inconel 718 alloy under cryogenic conditions was superior to that of its base-metal. In this case, UTS of hybrid joint (IS-G) at -100˚C was 900MPa. Consequently, UTS of Inconel 718 alloy is estimated to increase from -100˚C to a specific temperature below -100˚C. Therefore, Inconel 718 alloy is considered a pertinent material for the production of Lox Pipe under cryogenic conditions.